五氟苯甲醛

化合物

五氟苯甲醛是一种有机化合物,化学式为C6F5CHO。它可由五氟苯甲醇的催化氧化制得。[2][3]它可以被进一步氧化为五氟苯甲酸[4]它和苯甲硫醇三乙胺存在下于乙腈中反应,可以得到4-苯甲硫基四氟苯甲醛。[5]

五氟苯甲醛
识别
CAS号 653-37-2  checkY
PubChem 69558
ChemSpider 21106527
SMILES
 
  • O=CC=1C(F)=C(F)C(F)=C(F)C1F
性质
化学式 C7HF5O
摩尔质量 196.07 g·mol−1
外观 无色液体[1]
密度 1.751 g/mL
熔点 20 °C[1]
沸点 168~170 °C[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ 1.0 1.1 1.2 Pentafluorobenzaldehyde and its utilizing in organic synthesis. doi:10.1016/j.jfluchem.2008.12.013
  2. ^ Efficient aerial oxidation of different types of alcohols using ZnO nanoparticle–MnCO3-graphene oxide composites. doi:10.1002/aoc.5718
  3. ^ Synthesis, Characterization, and Relative Study on the Catalytic Activity of Zinc Oxide Nanoparticles Doped MnCO3, –MnO2, and –Mn2O3 Nanocomposites for Aerial Oxidation of Alcohols. doi:10.1155/2017/2937108.
  4. ^ Catalyst- and additive-free sunlight-induced autoxidation of aldehydes to carboxylic acids. doi:10.1039/D2GC01429G.
  5. ^ Synthesis of perfluoroaryl sulfides at electron-poor arenes via an SNAr step with an unexpected mechanism. 2022. doi:10.1016/j.xcrp.2022.101010