N-甲基脯氨酸甲酯
N-甲基脯氨酸甲酯是一种有机化合物，化学式为C7H13NO2。它可由脯氨酸甲酯、原甲酸三甲酯和氢气在三氟乙酸及催化剂存在下反应制得。[1]它和氟硼酸反应，可以得到相应的氟硼酸盐。[2]它和碘甲烷反应，可以得到N,N'-二甲基脯氨酸甲酯碘化物。[3]
| N-甲基脯氨酸甲酯 | |
|---|---|
| |
| 别名 | 1-甲基脯氨酸甲酯 |
| 识别 | |
| CAS号 | 933-94-8  114883-82-8（D） 27957-91-1（L）
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| 性质 | |
| 化学式 | C7H13NO2 |
| 摩尔质量 | 143.18 g·mol−1 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
- ^ Kadyrov, Renat; Moebus, Konrad. Reductive Alkylation of Amines with Carboxylic Ortho Esters. Advanced Synthesis & Catalysis, 2020. 362 (16): 3352-3357. doi:10.1002/adsc.202000510.
- ^ Kasperowicz-Frankowska, Katarzyna; Gzik, Anna; Dziemidkiewicz, Michal; Kolesinska, Beata; Kaminski, Zbigniew J. Synthesis of chiral triazine coupling reagents based on esters of N-alkylproline and their application in the enantioselective incorporation of D or L amino acid residue directly from racemic substrate. Acta Poloniae Pharmaceutica, 2014. 71 (6): 994-1003. ISSN 2353-5288
- ^ Martin, Lisandra L.; Lu, Jinzhen; Nafady, Ayman; Le, Thanh Hai; Siriwardana, Amal I.; Qu, Xiaohu; Traore, Daouda A. K.; Wilce, Matthew; Bond, Alan M. Novel Semiconducting Biomaterials Derived from a Proline Ester and Tetracyanoquinodimethane Identified by Handpicked Selection of Individual Crystals. Australian Journal of Chemistry, 2012. 65 (7): 935-941. doi:10.1071/ch12183.