N-甲基脯氨酸甲酯
N-甲基脯氨酸甲酯是一種有機化合物，化學式為C7H13NO2。它可由脯氨酸甲酯、原甲酸三甲酯和氫氣在三氟乙酸及催化劑存在下反應製得。[1]它和氟硼酸反應，可以得到相應的氟硼酸鹽。[2]它和碘甲烷反應，可以得到N,N'-二甲基脯氨酸甲酯碘化物。[3]
| N-甲基脯氨酸甲酯 | |
|---|---|
| |
| 別名 | 1-甲基脯氨酸甲酯 |
| 識別 | |
| CAS號 | 933-94-8  114883-82-8（D） 27957-91-1（L）
|
| 性質 | |
| 化學式 | C7H13NO2 |
| 摩爾質量 | 143.18 g·mol−1 |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
參考文獻
- ^ Kadyrov, Renat; Moebus, Konrad. Reductive Alkylation of Amines with Carboxylic Ortho Esters. Advanced Synthesis & Catalysis, 2020. 362 (16): 3352-3357. doi:10.1002/adsc.202000510.
- ^ Kasperowicz-Frankowska, Katarzyna; Gzik, Anna; Dziemidkiewicz, Michal; Kolesinska, Beata; Kaminski, Zbigniew J. Synthesis of chiral triazine coupling reagents based on esters of N-alkylproline and their application in the enantioselective incorporation of D or L amino acid residue directly from racemic substrate. Acta Poloniae Pharmaceutica, 2014. 71 (6): 994-1003. ISSN 2353-5288
- ^ Martin, Lisandra L.; Lu, Jinzhen; Nafady, Ayman; Le, Thanh Hai; Siriwardana, Amal I.; Qu, Xiaohu; Traore, Daouda A. K.; Wilce, Matthew; Bond, Alan M. Novel Semiconducting Biomaterials Derived from a Proline Ester and Tetracyanoquinodimethane Identified by Handpicked Selection of Individual Crystals. Australian Journal of Chemistry, 2012. 65 (7): 935-941. doi:10.1071/ch12183.