2-吡啶基溴化鎂

化合物

2-吡啶基溴化鎂是一種有機鎂化合物,化學式為C5H4BrMgN。它可由2-溴吡啶四氫呋喃中反應製得。[1]它和乙酰氯N-甲基吡咯烷酮存在下反應,可以得到2-乙酰基吡啶[2]

2-吡啶基溴化鎂
識別
CAS號 21970-13-8  checkY
SMILES
 
  • Br[Mg]C1=NC=CC=C1
性質
化學式 C5H4BrMgN
摩爾質量 182.3 g·mol−1
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

參考文獻

  1. ^ Cheng-Kun Li, Ze-Kun Tao, Adedamola Shoberu, Wei Zhang, and Jian-Ping Zou. Copper-Catalyzed Cross-Coupling of Alkyl and Phosphorus Radicals for C(sp3)–P Bond Formation. Org. Lett. 2022, 24, 32, 6083–6087. doi:10.1021/acs.orglett.2c02454.
  2. ^ Maravanhalli Sidde Gowda, Sushanth Sudhir Pande, Ramesha Andagar Ramakrishna and Kandikere Ramaiah Prabhu. Acylation of Grignard reagents mediated by N-methylpyrrolidone: A remarkable selectivity for the synthesis of ketones. Org. Biomol. Chem., 2011,9, 5365-5368. doi:10.1039/C1OB05780D.