克里格反应
克里格反应（Criegee reaction）[1]指邻二醇被四乙酸铅氧化，经过环状酯中间体，邻二醇的碳－碳键断裂，醇羟基转化为相应的醛、酮。反应是定量的，通常在乙酸或苯溶液中进行，可用于邻二醇的定量分析。
参见
参考资料
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- ^ R. Criegee in Newer Methods of Preparative Organic Chemistry vol. 1 (Interscience, New York, 1948) pp 12-20.
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- ^ S. Hatakeyama, H. Akimoto, Res. Chem. Intermed. 20, 503-524 (1994).
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- ^ R. Ponec et al., J. Org. Chem. 62, 2757 (1997).
- ^ R. M. Goodman, Y. Kishi, J. Am. Chem. Soc. 120, 9392 (1998).