三乙胺氧化物

化合物

三乙胺氧化物是一种氧化胺,化学式为C6H15NO。它可由三乙胺过氧化氢水溶液反应制得。[2]它可以在四氢呋喃中经碘化亚铜脱氧,得到三乙胺[3]它受热分解,生成三乙胺、N,N-二乙基羟胺、O,N-二乙基羟胺和O,N,N-三乙基羟胺,后者进一步分解为二乙胺乙醛[4]

三乙胺氧化物
识别
CAS号 2687-45-8  checkY
SMILES
 
  • CC[N+](CC)(CC)[O-]
性质
化学式 C6H15NO
摩尔质量 117.19 g·mol−1
熔点 165 °C(438 K)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ Arthur C. Cope, Hiok-Huang Lee. Amine Oxides. II. Conversion to N,N-Dialkylhydroxylamines 1. Journal of the American Chemical Society. 1957-02, 79 (4): 964–965 [2020-09-19]. ISSN 0002-7863. doi:10.1021/ja01561a050 (英语). 
  2. ^ Peter W. Moore, Yanxiao Jiao, Paul M. Mirzayans, Lexter Ng Qi Sheng, Jordan P. Hooker, Craig M. Williams. Selectivity Modulation of the Ley-Griffith TPAP Oxidation with N -Oxide Salts: Selectivity Modulation of the Ley-Griffith TPAP Oxidation with N -Oxide Salts. European Journal of Organic Chemistry. 2016-07, 2016 (20): 3401–3407 [2020-09-19]. doi:10.1002/ejoc.201600453 (英语). 
  3. ^ Sunil Kumar Singh, M. Srinivasa Reddy, Mangesh Mangle, K. Ravi Ganesh. Cu(I)-mediated deoxygenation of N-oxides to amines. Tetrahedron. 2007-01, 63 (1): 126–130 [2020-09-19]. doi:10.1016/j.tet.2006.10.031. (原始内容存档于2018-06-13) (英语). 
  4. ^ Boel Lindegård, Lennart Mathiasson, Jan Åke Jönsson, Bengt Åkesson. Controlled thermal degradation for the identification and quantification of amine N-oxides in urine. Journal of Chromatography A. 1990-01, 514: 293–304 [2020-09-19]. doi:10.1016/S0021-9673(01)89401-2. (原始内容存档于2018-06-25) (英语). 

参见