3-三丁基锡基吡啶
化合物
3-三丁基锡基吡啶是一种有机锡化合物,化学式为C17H31NSn。它可由3-溴吡啶和正丁基锂(或叔丁基锂[2])反应,再与三丁基氯化锡反应制得。[3]它和碘甲烷在乙醚中反应,可以得到1-甲基-3-三丁基锡基吡啶𬭩碘化物;和对甲苯磺酸甲酯在乙酸乙酯中反应,可以得到1-甲基-3-三丁基锡基吡啶𬭩对甲苯磺酸盐。[4]
3-三丁基锡基吡啶 | |
---|---|
![]() | |
识别 | |
CAS号 | 59020-10-9 ![]() |
PubChem | 3483848 |
SMILES |
|
性质 | |
化学式 | C17H31NSn |
摩尔质量 | 368.14 g·mol−1 |
外观 | 无色油状物[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
参考文献
- ^ Huifeng Yue; Chen Zhu; Magnus Rueping. Org. Lett. 2018, 20, 2, 385–388. doi:10.1021/acs.orglett.7b03669.
- ^ Nitration of heteroaryltrimethyltins by tetranitromethane and dinitrogen tetroxide: Mechanistic aspects, scope and limitations. European Journal of Organic Chemistry (2003), (9), 1711-1721. doi:10.1002/ejoc.200210611
- ^ Kim, Mi-Kyung; Kim, Yun-Hi; Kwon, Soon-Ki; Chu, Chang-Woong. Antiaromatic compounds and organic light-emitting devices comprising the same. 2015. US20150357578 A1.
- ^ A General Method of Synthesis of Regiospecifically N-Oxidized or N-Quaternized Polyazines by Palladium-Catalyzed Cross-Coupling of N-Oxidized or N-Quaternized Hetaryl Stannanes. Journal of Organic Chemistry (1995), 60 (11), 3487-3493