2-乙基噻吩
化合物
2-乙基噻吩是一种有机硫化合物,化学式为C6H8S。它可由2-乙酰基噻吩加氢还原制得,[2]或由噻吩、正丁基锂、溴乙烷反应得到。[3]它和碘苯、碳酸银在催化下反应,可以得到2-乙基-5-苯基噻吩。[4]
2-乙基噻吩 | |
---|---|
识别 | |
CAS号 | 872-55-9 |
SMILES |
|
性质 | |
化学式 | C6H8S |
摩尔质量 | 112.19 g·mol−1 |
沸点 | 134-135 °C[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
参考文献
- ^ Buu-Hoi, Ng. Ph.; Hoan, Nguyen; Khoi, Ng.-H. Potential nitrogen-heterocycle carcinogens. VII. Polycyclic carbazoles bearing ethyl groups, and thiophene isosters thereof. Journal of Organic Chemistry, 1950. 15: 957-961. ISSN 0022-3263.
- ^ Catalytic Reduction of 2-Acylthiophenes. J Am Chem Soc. 1951. 73 (11) doi:10.1021/ja01155a071
- ^ Oligothiophenes substituted with the thionitrile group: synthesis, characterization, and thin-film formation on gold substrates. Journal of Materials Chemistry. 2009. doi:10.1039/b908869e
- ^ Yanagisawa, Shuichi; Sudo, Tomoko; Noyori, Ryoji; Itami, Kenichiro. Direct C-H arylation of (hetero)arenes with aryl iodides via rhodium catalysis. J Am Chem Soc. 2006. doi:10.1021/ja064500p