2-乙基噻吩

化合物

2-乙基噻吩是一种有机硫化合物,化学式为C6H8S。它可由2-乙酰基噻吩加氢还原制得,[2]或由噻吩正丁基锂溴乙烷反应得到。[3]它和碘苯碳酸银在催化下反应,可以得到2-乙基-5-苯基噻吩。[4]

2-乙基噻吩
识别
CAS号 872-55-9  checkY
SMILES
 
  • S1C=CC=C1CC
性质
化学式 C6H8S
摩尔质量 112.19 g·mol−1
沸点 134-135 °C[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ Buu-Hoi, Ng. Ph.; Hoan, Nguyen; Khoi, Ng.-H. Potential nitrogen-heterocycle carcinogens. VII. Polycyclic carbazoles bearing ethyl groups, and thiophene isosters thereof. Journal of Organic Chemistry, 1950. 15: 957-961. ISSN 0022-3263.
  2. ^ Catalytic Reduction of 2-Acylthiophenes. J Am Chem Soc. 1951. 73 (11) doi:10.1021/ja01155a071
  3. ^ Oligothiophenes substituted with the thionitrile group: synthesis, characterization, and thin-film formation on gold substrates. Journal of Materials Chemistry. 2009. doi:10.1039/b908869e
  4. ^ Yanagisawa, Shuichi; Sudo, Tomoko; Noyori, Ryoji; Itami, Kenichiro. Direct C-H arylation of (hetero)arenes with aryl iodides via rhodium catalysis. J Am Chem Soc. 2006. doi:10.1021/ja064500p