2,2'-聯吡啶三羰基氯化錸

2,2'-聯吡啶三羰基氯化錸是一種配位化合物,化學式為C13H8ClN2O3Re。它可由氯化五羰基錸俄語Хлоро(пентакарбонил)рений2,2'-聯吡啶在氬氣保護下於甲苯中回流得到。[1]它是一種光敏劑英語Photosensitizer[2]它和一種三嗪COF的雜化材料可用於二氧化碳光化學還原反應[3]

2,2'-聯吡啶三羰基氯化錸
識別
CAS號 52064-98-9  checkY
PubChem none
性質
化學式 C13H8ClN2O3Re
摩爾質量 461.87 g·mol−1
外觀 黃色固體[1]
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

參考文獻

  1. ^ 1.0 1.1 Philipp Lang, Robin Giereth, Stefanie Tschierlei, Matthias Schwalbe. Unexpected wavelength dependency of the photocatalytic CO 2 reduction performance of the well-known (bpy)Re(CO) 3 Cl complex. Chemical Communications. 2019, 55 (5): 600–603 [2023-02-27]. ISSN 1359-7345. doi:10.1039/C8CC08742C (英語). 
  2. ^ Amal El Nahhas, Cristina Consani, Ana María Blanco-Rodríguez, Kyle M. Lancaster, Olivier Braem, Andrea Cannizzo, Michael Towrie, Ian P. Clark, Stanislav Záliš, Majed Chergui, Antonín Vlček. Ultrafast Excited-State Dynamics of Rhenium(I) Photosensitizers [Re(Cl)(CO) 3 (N,N)] and [Re(imidazole)(CO) 3 (N,N)] + : Diimine Effects. Inorganic Chemistry. 2011-04-04, 50 (7): 2932–2943 [2023-02-27]. ISSN 0020-1669. doi:10.1021/ic102324p. (原始內容存檔於2023-02-27) (英語). 
  3. ^ Sizhuo Yang, Wenhui Hu, Xin Zhang, Peilei He, Brian Pattengale, Cunming Liu, Melissa Cendejas, Ive Hermans, Xiaoyi Zhang, Jian Zhang, Jier Huang. 2D Covalent Organic Frameworks as Intrinsic Photocatalysts for Visible Light-Driven CO 2 Reduction. Journal of the American Chemical Society. 2018-11-07, 140 (44): 14614–14618 [2023-02-27]. ISSN 0002-7863. doi:10.1021/jacs.8b09705. (原始內容存檔於2022-10-23) (英語).