1-芘亚甲基丙二腈

化合物

1-芘亚甲基丙二腈是一种有机化合物,化学式为C20H10N2。它可由1-芘甲醛维基数据所列Q72503687丙二腈哌啶催化下于乙醇中反应制得。[3]它和N-溴代丁二酰亚胺乙腈水溶液中光照,C=C键发生断裂,生成1-芘甲醛。[4]

1-芘亚甲基丙二腈
识别
CAS号 27287-82-7  checkY
SMILES
 
  • N#CC(C#N)=CC1=CC=C2C=CC3=CC=CC=4C=CC1=C2C34
性质
化学式 C20H10N2
摩尔质量 278.31 g·mol−1
外观 红色固体[1]
熔点 254-255 °C[2]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ A. Franconetti; et al. Native and modified chitosan-based hydrogels as green heterogeneous organocatalysts for imine-mediated Knoevenagel condensation. Applied Catalysis A: General, 2016. 517. 176-186. doi:10.1016/j.apcata.2016.03.012.
  2. ^ Alan R. Katritzky; et al. Intramolecular charge transfer properties of dicyanovinyl-substituted aromatics. J. Phys. Chem. 1991, 95, 15, 5737–5742. doi:10.1021/j100168a007.
  3. ^ Dharini Arumugam; et al. Modulation of AIE and Intramolecular Charge Transfer of a Pyrene-Based Probe for Discriminatory Detection and Imaging of Oligomers and Amyloid Fibrils. ACS Appl. Bio Mater. 2024, 7, 10, 6343–6356. doi:10.1021/acsabm.4c00820.
  4. ^ Anupam Das; et al. Deconstruction of electron-deficient alkenes to carbonyl constituents by light-induced hydrogen atom transfer. Green Chem., 2023,25, 1078-1084. doi:10.1039/D2GC04424B.