5,15-二苯基-10,20-二(4-吡啶基)卟啉
5,15-二苯基-10,20-二(4-吡啶基)卟啉是一種有機化合物，化學式為C42H28N6。它可由吡咯、苯甲醛和4-吡啶甲醛按2:1:1化學計量比在丙酸中於150 °C回流反應，經柱分離後得到。[2]它和碘甲烷反應，得到相應的N-甲基吡啶鎓卟啉二碘化物。[3]它可以和金屬形成配位化合物。[4][5]
| 5,15-二苯基-10,20-二(4-吡啶基)卟啉 | |
|---|---|
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| 識別 | |
| CAS號 | 71410-72-5 
|
| 性質 | |
| 化學式 | C42H28N6 |
| 摩爾質量 | 616.71 g·mol−1 |
| 密度 | 1.293±0.06 g·cm−3（20 °C）[1] |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
參考文獻
- ^ Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 ((C) 1994-2021 ACD/Labs). Retrieved from SciFinder. [2021-07-03].
- ^ Zhou, Guojun; Wang, Bo; Cao, Rui. Acid Catalysis in Confined Channels of Metal–Organic Frameworks: Boosting Orthoformate Hydrolysis in Basic Solutions. Journal of the American Chemical Society. 2020, 142 (35): 14848–14853. ISSN 0002-7863. doi:10.1021/jacs.0c07257.
- ^ Amanda M. Slomp, Sandra M.W. Barreira, Luise Z.B. Carrenho, Camila C. Vandresen, Ingrid F. Zattoni, Stephanie M.S. Ló, Juliana C.C. Dallagnol, Diogo R.B. Ducatti, Alexandre Orsato, M. Eugênia R. Duarte, Miguel D. Noseda, Michel F. Otuki, Alan G. Gonçalves. Photodynamic effect of meso -(aryl)porphyrins and meso -(1-methyl-4-pyridinium)porphyrins on HaCaT keratinocytes. Bioorganic & Medicinal Chemistry Letters. 2017-01, 27 (2): 156–161 [2021-07-03]. doi:10.1016/j.bmcl.2016.11.094. （原始內容存檔於2018-06-10） （英語）.
- ^ Kang, Byungman; Totten, Ryan K.; Weston, Mitchell H.; Hupp, Joseph T.; Nguyen, SonBinh T. Cyclic metalloporphyrin dimers and tetramers: tunable shape-selective hosts for fullerenes. Dalton Transactions. 2012, 41 (39): 12156. ISSN 1477-9226. doi:10.1039/c2dt31126g.
- ^ Mariangela Boccalon, Elisabetta Iengo, Paolo Tecilla. New meso-substituted trans-A2B2 di(4-pyridyl)porphyrins as building blocks for metal-mediated self-assembling of 4 + 4 Re(i)–porphyrin metallacycles. Organic & Biomolecular Chemistry. 2013, 11 (24): 4056 [2021-07-03]. ISSN 1477-0520. doi:10.1039/c3ob40452h （英語）.