4-硝基苯甲醛
化合物
4-硝基苯甲醛是一種有機化合物,化學式為C7H5NO3,可以以4-硝基甲苯為原料製得。[3]
4-硝基苯甲醛 | |||
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IUPAC名 4-Nitrobenzaldehyde | |||
別名 | p-Nitrobenzaldehyde | ||
性質 | |||
化學式 | C7H5NO3 | ||
摩爾質量 | 151.12 g·mol−1 | ||
外觀 | 略帶黃色的晶體粉末 | ||
密度 | 1.546 g/cm3[1] | ||
熔點 | 103—106 °C(376—379 K)[2] | ||
沸點 | 300 °C(573 K)[1] | ||
磁化率 | −66.57·10−6 cm3/mol | ||
識別 | |||
CAS號 | 555-16-8 ![]() | ||
PubChem | 541 | ||
ChemSpider | 526 | ||
SMILES |
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InChI |
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InChIKey | BXRFQSNOROATLV-UHFFFAOYAO | ||
ChEBI | 66926 | ||
危險性 | |||
GHS危險性符號![]() | |||
H-術語 | H317, H319 | ||
P-術語 | P280, P305+351+338 | ||
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
它可以被水合肼在乙醇中還原為4-氨基苯甲醛,[4]或被硼氫化鈉還原為4-硝基苯甲醇,[5]硼氫化鈉也可將其還原為4-氨基苯甲醇[6]。它可以被過氧化氫氧化為4-硝基苯甲酸。[7]
參考文獻
- ^ 1.0 1.1 4-Nitrobenzaldehyde(555-16-8) (Date Accessed 17 April 2013)
- ^ 2.0 2.1 來源:Sigma-Aldrich Co., 4-Nitrobenzaldehyde (4 May 2011查閱).
- ^ 4-Nitrobenzaldehyd (頁面存檔備份,存於互聯網檔案館), Versuchsvorschrift aus: Organic Syntheses, Coll. Vol. 2, p. 441 (1943); Vol. 18, p. 61 (1938).
- ^ Shuo Chen, Li-Li Ling, Shun-Feng Jiang, Hong Jiang. Selective hydrogenation of nitroarenes under mild conditions by the optimization of active sites in a well defined Co@NC catalyst. Green Chemistry. 2020, 22 (17): 5730–5741 [2021-05-18]. ISSN 1463-9262. doi:10.1039/D0GC01835J (英語).
- ^ Naimi-Jamal, M. R.; Mokhtari, J.; Dekamin, Mohammad G. Fast and efficient method for quantitative reduction of carbonyl compounds by NaBH4 under solvent-free conditions. Proceedings of the International Electronic Conference on Synthetic Organic Chemistry, 11th, Nov. 1-30, 2007: a017/1-a017/5. ISBN 3-906980-19-7.
- ^ Wei-Guo Jia, Mei Li, Xue-Ting Zhi, Li-Li Gao, Jun Du. Copper(II) complex with oxazoline ligand: Synthesis, structures and catalytic activity for nitro compounds reduction. Journal of Molecular Structure. 2020-10, 1217: 128349 [2021-05-18]. doi:10.1016/j.molstruc.2020.128349. (原始內容存檔於2020-05-09) (英語).
- ^ Sagar Sharma, Nilotpal Barooah, Jubaraj B. Baruah. Tris(3,5-dimethylpyrazole)copper(II) nitrate: as an oxidation catalyst. Journal of Molecular Catalysis A: Chemical. 2005-03, 229 (1-2): 171–176 [2021-05-18]. doi:10.1016/j.molcata.2004.11.019. (原始內容存檔於2018-06-05) (英語).