1-溴-1-甲基環己烷
1-溴-1-甲基環己烷是一種有機化合物,化學式為C7H13Br,它是溴甲基環己烷的同分異構體之一。
1-溴-1-甲基環己烷 | |
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識別 | |
CAS號 | 931-77-1 |
PubChem | 12502129 |
SMILES |
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性質 | |
化學式 | C7H13Br |
摩爾質量 | 177.08 g·mol−1 |
沸點 | 42 °C(15 mmHg) 79 °C(38 mmHg)[1] |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
合成
1-溴-1-甲基環己烷可由1-甲基環己烯和氫溴酸反應得到,吸附劑使用矽膠。[2]它也可由甲基環己烷和溴在紫外線照射下反應得到。[3]
參考文獻
- ^ G. F. Dvorko, I. V. Koshchii, E. A. Ponomareva. Kinetics and mechanism of unimolecular heterolysis of cage-like compounds: XIX. Effect of the nucleofuge nature on the activation parameters of heterolysis of 1-halo-1-methylcyclohexanes in cyclohexane. Heterolysis rate ratio in aprotic and protic solvents. Russian Journal of Organic Chemistry. 2007-01, 43 (1): 50–55 [2023-02-17]. ISSN 1070-4280. doi:10.1134/S1070428007010046 (英語).
- ^ Kiyoshi Tanemura. Silica gel-mediated hydrohalogenation of unactivated alkenes using hydrohalogenic acids under organic solvent-free conditions. Tetrahedron Letters. 2018-12, 59 (49): 4293–4298 [2023-02-17]. doi:10.1016/j.tetlet.2018.10.043. (原始內容存檔於2022-10-23) (英語).
- ^ Manabe, Yoshiyuki; Kitawaki, Yuriko; Nagasaki, Masahiro; Fukase, Koichi; Matsubara, Hiroshi; Hino, Yoshiko; Fukuyama, Takahide; Ryu, Ilhyong. Revisiting the Bromination of C-H Bonds with Molecular Bromine by Using a Photo-Microflow System. Chemistry - A European Journal (Wiley). 2014-08-29, 20 (40): 12750–12753. ISSN 0947-6539. doi:10.1002/chem.201402303.