十一鎢釩磷酸

十一鎢釩磷酸是一種雜多酸,化學式為H4PW11VO40。它可以偏釩酸鈉磷酸氫二鈉鎢酸鈉硫酸在水溶液中反應得到。[2]它的酸性比相應的(取代)的雜多酸強。[3]它可被封裝進rht-MOF-1的空腔內用於燃料油的脫[4]

十一鎢釩磷酸
識別
CAS號 12398-73-1  checkY
性質
化學式 H4O40PVW11
摩爾質量 2748.16 g·mol−1
結構
晶體結構 三斜(十四水)[1]
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

參考文獻

  1. ^ Claude Rocchiccioli-Deltcheff, Michel Fournier. Catalysis by polyoxometalates. Part 3.—Influence of vanadium( V ) on the thermal stability of 12-metallophosphoric acids from in situ infrared studies. J. Chem. Soc., Faraday Trans. 1991, 87 (24): 3913–3920 [2022-09-24]. ISSN 0956-5000. doi:10.1039/FT9918703913 (英語). 
  2. ^ A. Sri Hari Kumar, K.T. Venkateswara Rao, K. Upendar, Ch. Sailu, N. Lingaiah, P.S. Sai Prasad. Nitration of phenol over silica supported H4PW11VO40 catalyst. Catalysis Communications. 2012-02, 18: 37–40 [2022-09-24]. doi:10.1016/j.catcom.2011.07.030. (原始內容存檔於2018-06-09) (英語). 
  3. ^ Dong Ryul Park, Sunyoung Park, Jung Ho Choi, In Kyu Song. Acidity of Group 5 Metal (V, Nb, Ta)-Substituted Keggin and Wells-Dawson Heteropolyacid (HPA) Catalysts and Their Application to Esterification of Acetic Acid with Ethanol. Catalysis Letters. 2010-04, 135 (3-4): 269–274 [2022-09-24]. ISSN 1011-372X. doi:10.1007/s10562-010-0299-y (英語). 
  4. ^ Yiyang Bai, Yuxiang Xin, Jiabin Liu, Liqiang Ma, Guangming Li. Construction of H 6 PW 9 V 3 O 40 @ rht ‐MOF‐1 for deep oxidative desulfurization of fuel oil. Applied Organometallic Chemistry. 2022-05, 36 (5) [2022-09-24]. ISSN 0268-2605. doi:10.1002/aoc.6633. (原始內容存檔於2022-09-27) (英語). 

拓展閱讀

  • Kozlenko, A. A.; Emmanuel, Tanor Baffoe; Polotebnova, N. A. Polarographic study of the properties of 11-tungstovanado(IV)​phosphoric acid complexes and their formation processes. Zhurnal Neorganicheskoi Khimii, 1992. 37 (11): 2524-2529.