丙基膦

化合物

丙基膦是一種有機磷化合物,化學式為C3H9P,它是異丙基膦希臘語Ισοπροπυλοφωσφίνη同分異構體。它可由丙基膦酸二乙酯氫化鋁鋰反應製得,[3]或通過磷二氫化鈉(或磷二氫化鋰[1])與鹵代丙烷反應得到。[4]它和甲醛鹽酸溶液中反應,可以得到三羥甲基丙基氯化鏻(CAS No. 91773-04-5)。[5]

丙基膦
別名 正丙基膦
識別
CAS號 40200-59-7  checkY
性質
化學式 C3H9P
摩爾質量 76.08 g·mol−1
沸點 54 °C(327 K)[1]
結構
偶極矩 1.09±0.06 D(氣態)[2]
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

參考文獻

  1. ^ 1.0 1.1 Kreutzkamp, Norbert. Preparation of monolithium phosphide and its conversion to primary aliphatic phosphines. Chemische Berichte, 1954. 87: 919-921.
  2. ^ Joseph G. Morse, R. W. Parry. Dipole Moment Studies. VI. Dipole Moments of the Propylphosphines. The Journal of Chemical Physics. 1972-12-15, 57 (12): 5367–5371 [2022-07-30]. ISSN 0021-9606. doi:10.1063/1.1678232. (原始內容存檔於2022-07-30) (英語). 
  3. ^ Robert P. Davies, Laura Patel, Andrew J. P. White. Preparations of Metal Trichalcogenophosphonates from Organophosphonate Esters. Inorganic Chemistry. 2012-11-05, 51 (21): 11594–11601 [2022-07-30]. ISSN 0020-1669. doi:10.1021/ic301504p. (原始內容存檔於2022-07-30) (英語). 
  4. ^ Uhlig, Frank; Herrmann, Eckhard. Primary alkylphosphines - RPH2. Synthetic Methods of Organometallic and Inorganic Chemistry, 1996. 3: 48-52. CODEN 63TCAS.
  5. ^ Petrov, K. A.; Parshina, V. A. Reactions of phosphines. I. Reaction of primary aliphatic phosphines with aldehydes and ketones. Zhurnal Obshchei Khimii, 1961. 31: 2729-2731. ISSN 0044-460X.