3-氯苯甲醛
化合物
3-氯苯甲醛是一種有機化合物,化學式為ClC6H4CHO,是氯苯甲醛的同分異構體之一。它可由3-氯苯甲醇的氧化反應製得。[3][4][5]它進一步氧化可以得到3-氯苯甲酸。[6]它和丙二腈反應,可以得到3-氯亞苄基丙二腈。[7]
3-氯苯甲醛 | |
---|---|
別名 | 間氯苯甲醛 |
識別 | |
CAS號 | 587-04-2 |
性質 | |
化學式 | C7H5ClO |
摩爾質量 | 140.57 g·mol−1 |
熔點 | 17—18 °C(290—291 K)[1] |
沸點 | 213—215 °C(486—488 K)[2] |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
參考文獻
- ^ Yongfei Wang, Hongbin Zhao, Zhizhi Hu, Masaru Kimura, Zhang Zhiqiang, Lei Peng, Koji Hiratsuka. A Convenient Formylation of 2-(Dibromomethyl)-6,11-diphenyl-5,12-naphthacenequinone Using N,N-Dimethylformamide or N,N-Dimethylacetamide: Synthesis of 2-Formyl Rubrene. Synthesis. 2011-01, 2011 (02): 287–291 [2021-06-12]. ISSN 0039-7881. doi:10.1055/s-0030-1258362. (原始內容存檔於2018-06-04) (英語).
- ^ Mahmood Tajbakhsh, Setareh Habibzadeh. Cleavage of C=N derivatives and Oxidation of Thiols in Water under Neutral Conditions with 1,4-dichloro-1,4-diazoniabicyclo[2,2,2]octane bischloride. Journal of Chemical Research. 2007-08, 2007 (8): 486–489 [2021-06-12]. ISSN 1747-5198. doi:10.3184/030823407X240890 (英語).
- ^ Babak Karimi, Farhad Kabiri Esfahani. Gold Nanoparticles Supported on the Periodic Mesoporous Organosilicas as Efficient and Reusable Catalyst for Room Temperature Aerobic Oxidation of Alcohols. Advanced Synthesis & Catalysis. 2012-05-07, 354 (7): 1319–1326 [2021-06-12]. doi:10.1002/adsc.201100802 (英語).
- ^ Takeshi Nishiguchi, Fumi Asano. Oxidation of alcohols by metallic nitrates supported on silica gel. The Journal of Organic Chemistry. 1989-03, 54 (7): 1531–1535 [2021-06-12]. ISSN 0022-3263. doi:10.1021/jo00268a011 (英語).
- ^ Katsuhiko Moriyama, Misato Takemura, Hideo Togo. Selective Oxidation of Alcohols with Alkali Metal Bromides as Bromide Catalysts: Experimental Study of the Reaction Mechanism. The Journal of Organic Chemistry. 2014-07-03, 79 (13): 6094–6104 [2021-06-12]. ISSN 0022-3263. doi:10.1021/jo5008064. (原始內容存檔於2022-04-25) (英語).
- ^ Mahdi Hajimohammadi, Zahra Ahmadi Khamesi, Parisa Nosrati. Efficient aerobic photooxygenation of aldehydes to carboxylic acids using cobalt(II) phthalocyanine sulfonate as a photosensitizer in organic-water biphasic media. Transition Metal Chemistry. 2019-02, 44 (2): 167–173 [2021-06-12]. ISSN 0340-4285. doi:10.1007/s11243-018-0281-x (英語).
- ^ Biswajit Laha, Sadhika Khullar, Alisha Gogia, Sanjay K. Mandal. Effecting structural diversity in a series of Co( ii )–organic frameworks by the interplay between rigidity of a dicarboxylate and flexibility of bis(tridentate) spanning ligands. Dalton Transactions. 2020, 49 (35): 12298–12310 [2021-06-12]. ISSN 1477-9226. doi:10.1039/D0DT02153A (英語).