六氰合鈷(III)酸鉈(I)
六氰合鈷(III)酸鉈(I)是一種配位化合物,化學式為Tl3[Co(CN)6],它具有f.c.c.晶格,空間群Fm3m。[2]它可由六氰合鈷(III)酸和碳酸亞鉈反應得到,[3]它也可由氰化鈷和氰化亞鉈溶液反應,再對溶液加熱得到:[4]
六氰合鈷(III)酸鉈(I) | |
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識別 | |
CAS號 | 14896-54-9 |
性質 | |
化學式 | Tl3[Co(CN)6] |
摩爾質量 | 828.19 g·mol⁻¹ |
溶解性(水) | 10.04 pts/100 pts H2O[1] |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
- Co(CN)2 + 4 TlCN → Tl4Co(CN)6
- 2 Tl4Co(CN)6 + 2 H2O → 2 Tl3Co(CN)6 + 2 TlOH + H2↑
參考文獻
- ^ A dictionary of chemical solubilities: inorganic. 1896. pp 131. Thallium cobalticyanide, Tl3Co(CN)6.
- ^ Dragulescu, C.; Tribunescu, P. Structure of the simple and mixed cobalticyanides of silver and thallium(法文). Rev. Chim. Minerale, 1965. 2 (1): 119-125.
- ^ P. S. Braterman, P. B. P. Phipps and R. J. P. Williams. 1147. Charge-transfer phenomena in some inorganic complexes. Part I. Electronic conduction in some complex cyanides. J. Chem. Soc., 1965, 6164-6169. doi:10.1039/JR9650006164
- ^ Sianokomplekse. South African Journal of Chemistry, 1966. 19 (2). doi:10.10520/AJA03794350_1157