苯硫醚

化合物

苯硫醚是一種有機化合物,化學式為C12H10S。它可由二苯基亞碸二苯基碸的還原反應得到,[2]或由碘苯苯硼酸存在下與反應製得。[3]它可以被氧化為相應的亞碸[4][5]

苯硫醚
識別
CAS號 139-66-2  checkY
性質
化學式 C12H10S
摩爾質量 186.27 g·mol−1
熔點 −25.9 °C(247.2 K)[1]
沸點 296 °C(569 K)[1]
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

參考文獻

  1. ^ 1.0 1.1 "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2022-09-16].
  2. ^ Kaiyue Yao, Ziliang Yuan, Shiwei Jin, Quan Chi, Bing Liu, Renjie Huang, Zehui Zhang. Efficient hydrodeoxygenation of sulfoxides into sulfides under mild conditions using heterogeneous cobalt–molybdenum catalysts. Green Chemistry. 2020, 22 (1): 39–43 [2022-09-16]. ISSN 1463-9262. doi:10.1039/C9GC02465D (英語). 
  3. ^ Abed Rostami, Amin Rostami, Arash Ghaderi, Mohammad Ali Zolfigol. Ligand-free Cu-catalyzed odorless synthesis of unsymmetrical sulfides through cross-coupling reaction of aryl/benzyl/alkyl halides with an aryl boronic acid/S 8 system as a thiolating agent in PEG. RSC Advances. 2015, 5 (46): 37060–37065 [2022-09-16]. ISSN 2046-2069. doi:10.1039/C5RA05244K (英語). 
  4. ^ Hadi Kargar, Azar Kaka-Naeini, Mehdi Fallah-Mehrjardi, Reza Behjatmanesh-Ardakani, Hadi Amiri Rudbari, Khurram Shahzad Munawar. Oxovanadium and dioxomolybdenum complexes: synthesis, crystal structure, spectroscopic characterization and applications as homogeneous catalysts in sulfoxidation. Journal of Coordination Chemistry. 2021-05-19, 74 (9-10): 1563–1583 [2022-09-16]. ISSN 0095-8972. doi:10.1080/00958972.2021.1915488 (英語). 
  5. ^ Imran Khan, Vivek Das, Anne‐Lucie Teillout, Israël‐Martyr Mbomekallé, Pedro Oliveira, Subash Chandra Sahoo, Firasat Hussain. Tetrameric Lanthanide‐Substituted Silicotungstate {Ln 8 Si 4 W 40 } Nanoclusters: Synthesis, Structural Characterization, Electrochemistry, and Catalytic Application for Oxidation of Thioethers. European Journal of Inorganic Chemistry. 2021-03-19, 2021 (11): 1071–1081 [2022-09-16]. ISSN 1434-1948. doi:10.1002/ejic.202001096 (英語).