甘氨酰纈氨酰甘氨酸

甘氨酰纈氨酰甘氨酸(Gly-Val-Gly)是一種三肽,化學式為C9H17N3O4。它可以甘氨酸苄酯對甲苯磺酸鹽和叔丁氧羰基-L-纈氨酸為原料,經多步反應製得,[1]它在水中結晶可以得到一水合物。[2]它可以和N-溴代丁二酰亞胺反應,得到甲醛異丁醛[3]

甘氨酰纈氨酰甘氨酸
別名 N-(N-甘氨酰纈氨酰)甘氨酸
識別
CAS號 28112-97-2S checkY
性質
化學式 C9H17N3O4
摩爾質量 231.25 g·mol−1
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

參考文獻

  1. ^ Gowda, B K Kempe; Rangappa, K S; Gowda, D Channe. Kinetic studies on oxidation of Gly-Val-Gly, Gly-Phe-Gly and Ala-Val-Gly using Mn(III)頁面存檔備份,存於網際網路檔案館). Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry (2002), 41B (5), 1039-1044.
  2. ^ Jin L. Liu, Andrew W. Hakin, Gavin R. Hedwig. Volumetric properties of tripeptides with non-polar side-chains: Partial molar volumes at T=(288.15 to 313.15) K and partial molar expansions at T = 298.15 K of some peptides of sequence gly-X-gly in aqueous solution. The Journal of Chemical Thermodynamics, 2009. 41 (11): 1232-1238. doi:10.1016/j.jct.2009.05.011.
  3. ^ Kumara, M. N.; Linge Gowda, N. S.; Mantelingu, K.; Rangappa, Kanchugara Koppal S. N-Bromosuccinimide assisted oxidation of tripeptides and their amino acid analogs: synthesis, kinetics, and product studies. Journal of Molecular Catalysis A: Chemical (2009), 309(1-2), 172-177. doi:10.1016/j.molcata.2009.05.024.