三氟甲磺酸亞鉈
化合物
三氟甲磺酸亞鉈是一種具有吸濕性的鉈化合物，化學式為CF3SO3Tl。它可由碳酸亞鉈和三氟甲磺酸反應製得。[1]
| 三氟甲磺酸亞鉈 | |
|---|---|
| 識別 | |
| CAS號 | 73491-36-8 
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| SMILES |
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| 性質 | |
| 化學式 | CF3O3STl |
| 摩爾質量 | 353.45 g·mol−1 |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
它和二甲硫醚氯化亞金、六苯基-1,4,7,10-四磷雜癸烷（L）反應，可以得到[Au4L2](CF3SO3)4。[2]它和Mo2Ni(dpa)4Cl2（dpa=二(2-吡啶基)胺）在乙腈中反應，可以得到Mo2Ni(dpa)4(CF3SO3)2。[3]
參考文獻
- ^ F. Albert Cotton, Naresh S. Dalal, Penglin Huang, Sergey A. Ibragimov, Carlos A. Murillo, Paula M. B. Piccoli, Chris M. Ramsey, Arthur J. Schultz, Xiaoping Wang, and Qinliang Zhao. Better Understanding of the Species with the Shortest Re26+ Bonds and Related Re27+ Species with Tetraguanidinate Paddlewheel Structures. Inorg. Chem. 2007, 46, 5, 1718–1726. doi:10.1021/ic062319b.
- ^ Walter Schuh, Holger Kopacka, Klaus Wurst, Paul Peringer. Homochiral Self Recognition in Gold-Phosphane-Helicates. European Journal of Inorganic Chemistry, 2002. 8. 2202-2206. doi:10.1002/1099-0682(200208)2002:8<2202::AID-EJIC2202>3.0.CO;2-G.
- ^ Jill A. Chipman and John F. Berry. Facile Axial Ligand Substitution in Linear Mo≣Mo–Ni Complexes. Inorg. Chem. 2018, 57, 15, 9354–9363. doi:10.1021/acs.inorgchem.8b01331.
拓展閱讀
- Petr Vaňura, David Sýkora, Tereza Uhlíková. Reaction of the thallium(I) cation with [2.2]paracyclophane: Experimental and theoretical study. Inorganica Chimica Acta, 2022. 543. 121205. doi:10.1016/j.ica.2022.121205.
- Seifert, Tim P.; Knoefel, Nicolai D. ; Feuerstein, Thomas J. ; Reiter, Kevin; Lebedkin, Sergei; Gamer, Michael T. ; Boukis, Andreas C.; Weigend, Florian; Kappes, Manfred M.; Roesky, Peter W. Size Matters: From Two-Dimensional Au(I)-Tl(I) Metallopolymers to Molecular Complexes by Simple Variation of the Steric Demand. Chemistry - A European Journal, 2019. 25 (15): 3799-3808. doi:10.1002/chem.201805984.