丁酸鈾酰
丁酸鈾酰是一種配位化合物,化學式為UO2(C3H7COO)2,存在無水物和二水合物。[2]它可以形成配離子[UO2(C3H7COO)3]−。[3]
丁酸鈾酰 | |
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識別 | |
CAS號 | 10007-92-8 |
性質 | |
化學式 | C8H14O6U |
摩爾質量 | 444.22 g·mol−1 |
外觀 | 黃色晶體(二水)[1] |
密度 | 2.323 g·cm−3(二水,100 K)[1] |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
製備
參考文獻
- ^ 1.0 1.1 1.2 A. V. Savchenkov, A. V. Vologzhanina, V. N. Serezhkin, D. V. Pushkin, L. B. Serezhkina. X-Ray diffraction and IR-spectroscopic studies of UO2(n-C3H7COO)2(H2O)2 and Mg(H2O)6[UO2(n-C3H7COO)3]2. Crystallography Reports. 2014-03, 59 (2): 190–195 [2023-02-23]. ISSN 1063-7745. doi:10.1134/S1063774514010131 (英語).
- ^ Arenas, J. F.; Rojas, R. M.; Bermudez, J. Infrared spectra of butyrate complexes of uranium, bis(butyrate)dioxouranium(VI) [UO2(C3H7COO)2], bis(butyrate)diaquodioxouranium(VI) [UO2(C3H7COO)2(H2O)2], and tris(butyrate)dioxouranate(VI) [UO2(C3H7COO)3]. Anales de Quimica. 1973. 69 (7-8): 869-878. ISSN 0365-4990. CODEN ANQUBU.
- ^ D. V. Pushkin, A. V. Vologzhanina, L. B. Serezhkina, A. V. Savchenkov, A. A. Korlyukov, V. N. Serezhkin. Synthesis, crystal structure, and IR spectral study of Na[(UO2)(C3H7COO)3] · 0.25H2O and K[(UO2)(C3H7COO)3]. Russian Journal of Inorganic Chemistry. 2012-07, 57 (7): 939–944 [2023-02-23]. ISSN 0036-0236. doi:10.1134/S0036023612070169 (英語).