二苄基碲
二苄基碲是一种有机化合物，化学式为(C6H5CH2)2Te。它可由氯化苄、碲、水合肼和氢氧化钾反应制得。[2]氯化苄、碲和碘化钠在110 °C反应，得到二苄基二碘化碲，它经硫化钠还原，也能得到二苄基碲。[3]
| 二苄基碲 | |
|---|---|
| 别名 | 二苄基碲醚 |
| 识别 | |
| CAS号 | 62654-03-9 
|
| 性质 | |
| 化学式 | C14H14Te |
| 摩尔质量 | 309.86 g·mol−1 |
| 外观 | 浅黄色针状晶体[1] |
| 熔点 | 53—53.5 °C（326.1—326.6 K）[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
- ^ 1.0 1.1 Chugaev, L.; Chlopin, W. Reducing power of sulfurous acid. I. Action of sodium hydrosulfite on tellurium and selenium. Berichte der Deutschen Chemischen Gesellschaft. 1914. 47: 1269-1275.
- ^ Korchevin, N. A.; Podkuiko, P. A.; Stankevich, V. K.; Deryagina, E. N.; Trofimov, B. A. New route to diorganyl selenides and tellurides. Zhurnal Obshchei Khimii, 1995. 65 (1): 99-101.
- ^ Kulkarni, Y. D., & Srivastava, S. (1985). Synthesis & Characterization of Some Stable Dibenzyltellurium (II&IV) Derivatives & Their Antibacterial Activity. Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical. 1985. 24A (8): 710-712.
- ^ Douglas C. Gordon, Rein U. Kirss, Duncan W. Brown. Synthesis and characterization of volatile trifluoromethyl alkyl tellurides. Organometallics. 1992-08, 11 (8): 2947–2949 [2023-03-12]. ISSN 0276-7333. doi:10.1021/om00044a043. （原始内容存档于2023-03-12） （英语）.
拓展阅读
- Bernard Gautheron, Gerard Tainturier, Chantal Degrand. Ultrasound-induced electrochemical synthesis of the anions selenide (Se22-, Se2-), and telluride (Te22-, and Te2-). Journal of the American Chemical Society. 1985-09, 107 (19): 5579–5581 [2023-03-12]. ISSN 0002-7863. doi:10.1021/ja00305a070 （英语）.