1,1'-联萘-2,2'-二基磷酸氢酯

化合物

1,1'-联萘-2,2'-二基磷酸氢酯联萘酚磷酸酯是一种有机化合物,化学式为C20H13O4P。它可由1,1'-联-2-萘酚三氯氧磷吡啶的存在下于四氢呋喃(或三乙胺二氯甲烷[3])中反应,酸化后得到。[4]

1,1'-联萘-2,2'-二基磷酸氢酯
英文名 1,1'-Binaphthalene-2,2'-diyl hydrogen phosphate
别名 联萘酚磷酸酯
识别
CAS号 35193-63-6  checkY
39648-67-4R checkY
35193-64-7S checkY
SMILES
 
  • OP1(=O)Oc2ccc3ccccc3c2-c4c(O1)ccc5ccccc45
性质
化学式 C20H13O4P
摩尔质量 348.29 g·mol−1
密度 1.49±0.1 g·cm−3[1]
熔点 >180 °C[2]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 ((C) 1994-2020 ACD/Labs). [2020-12-16].
  2. ^ Thomas Dorn, Christoph Janiak, Khalid Abu-Shandi. Hydrogen-bonding, π-stacking and Cl–-anion–π interactions of linear bipyridinium cations with phosphate, chloride and [CoCl4]2– anions. CrystEngComm. 2005, 7 (106): 633 [2020-12-16]. ISSN 1466-8033. doi:10.1039/b508944a (英语). 
  3. ^ Mikami, Koichi; Motoyama, Yukihiro; Brunel, Jean Michel; Mollat du Jourdin, Xavier. (R)-1,1'-Bi-2,2'-naphthol. e-EROS Encyclopedia of Reagents for Organic Synthesis, 2015. 1-19. ISBN 978-0-470-84289-8.
  4. ^ Fabian Scharinger, Ádám Márk Pálvölgyi, Veronika Zeindlhofer, Michael Schnürch, Christian Schröder, Katharina Bica‐Schröder. Counterion Enhanced Organocatalysis: A Novel Approach for the Asymmetric Transfer Hydrogenation of Enones. ChemCatChem. 2020-07-21, 12 (14): 3776–3782 [2020-12-16]. ISSN 1867-3880. PMC 7507862 . PMID 32999691. doi:10.1002/cctc.202000414 (英语).