灰叶草素

灰叶草素(英語:Tephrosin,也称为羟基鱼藤素)是一种有机化合物,分子式C23H22O7,属于鱼藤酮类化合物英语Rotenoid,比鱼藤素多一个7α位的羟基,存在于灰毛豆Tephrosia purpurea[2]威氏鐵富豆Tephrosia vogelii[3]等植物的种子中。

灰叶草素
IUPAC名
7a-Hydroxy-9,10-dimethoxy-3,3-dimethyl-13,13a-dihydro-3H,7aH-pyrano[2,3-c;6,5-f']dichromen-7-one
别名 12aβ-hydroxydeguelin[1]
识别
CAS号 76-80-2  checkY
PubChem 114909
ChemSpider 102858
SMILES
 
  • CC1(C=CC2=C(O1)C=CC3=C2O[C@@H]4COC5=CC(=C(C=C5[C@@]4(C3=O)O)OC)OC)C
InChI
 
  • 1/C23H22O7/c1-22(2)8-7-12-15(30-22)6-5-13-20(12)29-19-11-28-16-10-18(27-4)17(26-3)9-14(16)23(19,25)21(13)24/h5-10,19,25H,11H2,1-4H3/t19-,23-/m1/s1
InChIKey AQBZCCQCDWNNJQ-AUSIDOKSBD
ChEBI 9442
KEGG C10535
性质
化学式 C23H22O7
摩尔质量 410.41658 g/mol g·mol⁻¹
相关物质
相关化学品 鱼藤素Toxicarol維基數據所列Q27108457
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ Cabizza, Maddalena; Alberto Angioni; Marinella Melis; Marco Cabras; Carlo V. Tuberoso; Paolo Cabras. Rotenone and rotenoids in cubè resins, formulations, and residues on olives. Journal of Agricultural and Food Chemistry. 2004, 52 (2): 288–293. PMID 14733510. doi:10.1021/jf034987a. 
  2. ^ Ahmad, V. U.; Z. Ali; S. R. Hussaini; F. Iqbal; M. Zahid; M. Abbas; N. Saba. Flavonoids of Tephrosia purpurea. Fitoterapia. 1999-08-01, 70 (4): 443–445. doi:10.1016/S0367-326X(99)00046-5. 
  3. ^ Lambert, Nadine; Trouslot, Marie-France; Nef-Campa, Claudine; Chrestin, Hervé. Production of rotenoids by heterotrophic and photomixotrophic cell cultures of tephrosia vogelii. Phytochemistry. 1993-12, 34 (6): 1515–1520. doi:10.1016/S0031-9422(00)90838-0.