十六氢芘

化合物

十六氢芘(英语:Perhydropyrene)是一种四环有机化合物,化学式为C16H26,相当于的所有不饱和键变为饱和[1]。它可由催化下于庚烷中加热、加压氢化得到。[2]

十六氢芘
Skeletal formula of perhydropyrene
Ball-and-stick model of the perhydropyrene molecule
IUPAC名
Hexadecahydropyrene
识别
CAS号 2435-85-0  checkY
PubChem 75524
ChemSpider 68050
SMILES
 
  • C2CCC3CCC1C4C(CCC1)CCC2C34
InChI
 
  • 1S/C16H26/c1-3-11-7-9-13-5-2-6-14-10-8-12(4-1)15(11)16(13)14/h11-16H,1-10H2
性质
化学式 C16H26
摩尔质量 218.38 g·mol−1
密度 0.962 g/mL
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ Ayub, Khurshid; Zhang, Rui; Robinson, Stephen G.; Twamley, Brendan; Williams, Richard Vaughan; Mitchell, Reginald H. Suppressing the Thermal Metacyclophanediene to Dihydropyrene Isomerization: Synthesis and Rearrangement of 8,16-Dicyano(2.2)metacyclophane-1,9-diene and Evidence Supporting the Proposed Biradicaloid Mechanism. The Journal of Organic Chemistry. 2008, 73 (2): 451–6. PMID 18154301. doi:10.1021/jo7019459. 
  2. ^ McGrady, Gerard Sean; et al. Carbonaceous material upgrading using supercritical fluids. US20120279902 A1. 2012-11-08

外部链接