四氫合鋁酸鈣

四氫合鋁酸鈣
識別
CAS號	16941-10-9 ?
性質
化學式	Ca[AlH4]2
摩爾質量	102.10 g·mol⁻¹
外觀	無色晶體（四(四氫呋喃)合物）
沸點	472 K（分解）
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

四氫合鋁酸鈣是一種無機化合物，化學式為Ca[AlH₄]₂，它是鈣的鋁氫化物之一。它可由氫化鋁鈉和氯化鈣以2:1化學計量比在1 MPa的氫氣氣氛中球磨得到，^[3]或在四氫呋喃中反應製得。^[4]它在和硼氫化鋰的混合物熱分解中，檢測到了[B₁₂H₁₂]²⁻離子。^[5]

參考文獻

^ Maximilian Fichtner, Christoph Frommen, Olaf Fuhr. Synthesis and Properties of Calcium Alanate and Two Solvent Adducts. Inorganic Chemistry. 2005-05-01, 44 (10): 3479–3484 [2023-01-05]. ISSN 0020-1669. doi:10.1021/ic048291q. （原始內容存檔於2023-01-05）（英語）.
^ Naoto Morisaku, Kenji Komiya, Yu Zhan Li, Hiroshi Yukawa, Masahiko Morinaga, Kazutaka Ikeda, Shinichi Orimo. Synthesis and Decomposition of Pure Ca(AlH4)2. Advanced Materials Research. 2007-10, 26–28: 869–872 [2023-01-05]. ISSN 1662-8985. doi:10.4028/www.scientific.net/AMR.26-28.869. （原始內容存檔於2023-01-05）.
^ Changxu Li, Xuezhang Xiao, Peiqian Ge, Jingwen Xue, Shouquan Li, Hongwei Ge, Lixin Chen. Investigation on synthesis, structure and catalytic modification of Ca(AlH4)2 complex hydride. International Journal of Hydrogen Energy. 2012-01, 37 (1): 936–941 [2023-01-05]. doi:10.1016/j.ijhydene.2011.03.151. （原始內容存檔於2022-06-15）（英語）.
^ K. Komiya, N. Morisaku, Y. Shinzato, K. Ikeda, S. Orimo, Y. Ohki, K. Tatsumi, H. Yukawa, M. Morinaga. Synthesis and dehydrogenation of M(AlH4)2 (M = Mg, Ca). Journal of Alloys and Compounds. 2007-10,. 446-447: 237–241 [2023-01-05]. doi:10.1016/j.jallcom.2007.01.119. （原始內容存檔於2022-06-15）（英語）.
^ Son-Jong Hwang, Robert C. Bowman, Joseph W. Reiter, Rijssenbeek, Grigorii L. Soloveichik, Ji-Cheng Zhao, Houria Kabbour, Channing C. Ahn. NMR Confirmation for Formation of [B 12 H 12 ] 2- Complexes during Hydrogen Desorption from Metal Borohydrides. The Journal of Physical Chemistry C. 2008-03-01, 112 (9): 3164–3169 [2023-01-05]. ISSN 1932-7447. doi:10.1021/jp710894t. （原始內容存檔於2023-01-05）（英語）.

[1] Maximilian Fichtner, Christoph Frommen, Olaf Fuhr. Synthesis and Properties of Calcium Alanate and Two Solvent Adducts. Inorganic Chemistry. 2005-05-01, 44 (10): 3479–3484 [2023-01-05]. ISSN 0020-1669. doi:10.1021/ic048291q. （原始內容存檔於2023-01-05）（英語）.

[2] Naoto Morisaku, Kenji Komiya, Yu Zhan Li, Hiroshi Yukawa, Masahiko Morinaga, Kazutaka Ikeda, Shinichi Orimo. Synthesis and Decomposition of Pure Ca(AlH4)2. Advanced Materials Research. 2007-10, 26–28: 869–872 [2023-01-05]. ISSN 1662-8985. doi:10.4028/www.scientific.net/AMR.26-28.869. （原始內容存檔於2023-01-05）.

[3] Changxu Li, Xuezhang Xiao, Peiqian Ge, Jingwen Xue, Shouquan Li, Hongwei Ge, Lixin Chen. Investigation on synthesis, structure and catalytic modification of Ca(AlH4)2 complex hydride. International Journal of Hydrogen Energy. 2012-01, 37 (1): 936–941 [2023-01-05]. doi:10.1016/j.ijhydene.2011.03.151. （原始內容存檔於2022-06-15）（英語）.

[4] K. Komiya, N. Morisaku, Y. Shinzato, K. Ikeda, S. Orimo, Y. Ohki, K. Tatsumi, H. Yukawa, M. Morinaga. Synthesis and dehydrogenation of M(AlH4)2 (M = Mg, Ca). Journal of Alloys and Compounds. 2007-10,. 446-447: 237–241 [2023-01-05]. doi:10.1016/j.jallcom.2007.01.119. （原始內容存檔於2022-06-15）（英語）.

[5] Son-Jong Hwang, Robert C. Bowman, Joseph W. Reiter, Rijssenbeek, Grigorii L. Soloveichik, Ji-Cheng Zhao, Houria Kabbour, Channing C. Ahn. NMR Confirmation for Formation of [B 12 H 12 ] 2- Complexes during Hydrogen Desorption from Metal Borohydrides. The Journal of Physical Chemistry C. 2008-03-01, 112 (9): 3164–3169 [2023-01-05]. ISSN 1932-7447. doi:10.1021/jp710894t. （原始內容存檔於2023-01-05）（英語）.

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