二氯化二(1,3,5-三氮雜-7-磷雜金剛烷)合鉑
二氯化二(1,3,5-三氮雜-7-磷雜金剛烷)合鉑是一種配位化合物，化學式為PtCl2P2C12H24N6。它可由四氯合鉑(II)酸鉀和1,3,5-三氮雜-7-磷雜金剛烷（PTA）在乙醇中反應製得，[1]，或通過PtCl2(COD)（COD=1,5-環辛二烯）和PTA反應得到。[2]它在0.1 mol/L的鹽酸溶液中可以結晶出無色的cis-[PtCl2(PTAH)2]Cl2晶體。[1]它的配位氯可以被含硫配體取代。[3]
| 二氯化二(1,3,5-三氮雜-7-磷雜金剛烷)合鉑 | |
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2Cl2.svg)
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| 識別 | |
| CAS號 | 194346-40-2 
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| 性質 | |
| 化學式 | H24Cl2N6P2Pt |
| 摩爾質量 | 436.17 g·mol−1 |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
參考文獻
- ^ 1.0 1.1 Donald J. Darensbourg; et al. Water-Soluble Organometallic Compounds. 6.1 Synthesis, Spectral Properties, and Crystal Structures of Complexes of 1,3,5-Triaza-7-phosphaadamantane with Group 10 Metals. Inorg. Chem. 1997, 36, 19, 4218–4226. doi:10.1021/ic970238x.
- ^ Don A. Krogstad; et al. Intramolecular hydroamination of alkynylamines in aqueous media catalyzed by platinum(II) 1,3,5-triaza-7-phosphaadamantane (PTA) complexes. Inorganic Chemistry Communications, 2005. 8 (1): 65-69. doi:10.1016/j.inoche.2004.11.006.
- ^ Elena Guerrero; et al. trans-Thionate Derivatives of Pt(II) and Pd(II) with Water-Soluble Phosphane PTA and DAPTA Ligands: Antiproliferative Activity against Human Ovarian Cancer Cell Lines. Inorg. Chem. 2013, 52, 11, 6635–6647. doi:10.1021/ic4006746.