硒化亞鐵

化合物

硒化亞鐵是一種無機化合物,化學式為FeSe。[1]它可由的化合反應製備。[2]

硒化亞鐵
IUPAC名
Iron(II) selenide
識別
CAS號 1310-32-3  checkY
PubChem 14795
SMILES
 
  • [Fe]=[Se]
InChI
 
  • 1S/Fe.Se
InChIKey WALCGGIJOOWJIN-UHFFFAOYSA-N
EINECS 215-177-1
性質
化學式 FeSe
摩爾質量 134.81 g·mol⁻¹
外觀 黑色晶體
密度 4.72 g/cm3
熔點 965 °C(1238 K)
溶解性 0.975 g/100 mL
結構
晶體結構 六方
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

超導性

β-FeSe 是最簡單的鐵基超導體,但具有不同的屬性。[3]常壓下,它在 8 K以下超導;[4]但通過嵌入[3]或在高壓下淬火[5],它的超導轉變溫度 (Tc)急劇增加到 38 K,[6]嵌入和高壓淬火的結合會使超導轉變溫度上升到 48 K。[3]

2013年有報道稱,在SrTiO3外延生長的FeSe單原子層具有超導性,鐵基超導體的轉變溫度為 70 K。[7]這一發現引起了極大的關注,據2014年的報道,該系統的超導轉變溫度超過 100K。[8]

參考文獻

  1. ^ University of Akron Chemical Database[永久失效連結]
  2. ^ Gorokh, A. V.; Kabanova, L. M.; Dobosh, V. G. Reaction of iron with selenium at 400-1400°. Doklady Akademii Nauk SSSR, 1966. 169 (3): 639-640.
  3. ^ 3.0 3.1 3.2 Yu. V. Pustovit; A. A. Kordyuk. Metamorphoses of electronic structure of FeSe-based superconductors (Review article). Low Temp. Phys. 2016, 42 (11): 995. Bibcode:2016LTP....42..995P. S2CID 119184569. arXiv:1608.07751 . doi:10.1063/1.4969896. 
  4. ^ F.-C. Hsu; et al. Superconductivity in the PbO-type structure α-FeSe. Proc. Natl. Acad. Sci. USA. 2008, 105 (38): 14262–14264. Bibcode:2008PNAS..10514262H. PMC 2531064 . PMID 18776050. arXiv:0807.2369 . doi:10.1073/pnas.0807325105 . 
  5. ^ Deng, Liangzi; Bontke, Trevor; Dahal, Rabin; Xie, Yu; Gao, Bin; Li, Xue; Yin, Ketao; Gooch, Melissa; Rolston, Donald; Chen, Tong; Wu, Zheng; Ma, Yanming; Dai, Pengcheng; Chu, Ching-Wu. Pressure-induced high-temperature superconductivity retained without pressure in FeSe single crystals. Proceedings of the National Academy of Sciences. 13 July 2021, 118 (28): e2108938118 [11 July 2021]. PMC 8285973 . PMID 34234019. doi:10.1073/pnas.2108938118. (原始內容存檔於2021-07-11).  已忽略未知參數|pmc-embargo-date= (幫助)
  6. ^ Medvedev, S.; McQueen, T. M.; Troyan, I. A.; Palasyuk, T.; Eremets, M. I.; Cava, R. J.; Naghavi, S.; Casper, F.; Ksenofontov, V.; Wortmann, G.; Felser, C. Electronic and Magnetic Phase Diagram of β-Fe1.01Se with superconductivity at 36.7 K under pressure. Nature Materials. 2009, 8 (8): 630–633. Bibcode:2009NatMa...8..630M. PMID 19525948. arXiv:0903.2143 . doi:10.1038/nmat2491. 
  7. ^ R. Peng; et al. Enhanced superconductivity and evidence for novel pairing in single-layer FeSe on SrTiO3 thin film under large tensile strain. Physical Review Letters. 2014, 112 (10): 107001. Bibcode:2014PhRvL.112j7001P. PMID 24679321. S2CID 118446521. arXiv:1310.3060 . doi:10.1103/PhysRevLett.112.107001. 
  8. ^ J.-F. Ge; et al. Superconductivity in single-layer films of FeSe with a transition temperature above 100 K. Nature Materials. 2014, 14 (3): 285–9. Bibcode:2015NatMa..14..285G. PMID 25419814. arXiv:1406.3435 . doi:10.1038/nmat4153.