二苯并环庚烯

化合物

二苯并环庚烯(英语:Dibenzocycloheptene,dibenzocycloheptadiene,dibenzosuberane)是一种三环有机化合物,化学式为C15H14,是许多三环类抗抑郁药(TCA)的结构母体[1]。它可由二苯并环庚酮还原得到。[2]

二苯并环庚烯
Skeletal formula of dibenzocycloheptene
Ball-and-stick model of the dibenzocycloheptene molecule
IUPAC名
10,11-Dihydro-5H-dibenzo[a,d][7]annulene
别名 10,11-二氢-5H-二苯并[a,d]环庚烯
1,2:4,5-二苯并环庚烷
识别
CAS号 833-48-7  checkY
PubChem 70029
ChemSpider 63219
SMILES
 
  • c1cc3c(cc1)Cc2c(cccc2)CC3
InChI
 
  • InChI=1S/C15H14/c1-3-7-14-11-15-8-4-2-6-13(15)10-9-12(14)5-1/h1-8H,9-11H2
性质
化学式 C15H14
摩尔质量 194.27 g·mol⁻¹
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ Chen, Chien-Tien; Chou, Y-Chen. C2-Symmetric Dibenzosuberane-Based Helicenes as Potential Chirochromic Optical Switches. Journal of the American Chemical Society. 2000, 122 (32): 7662–7672. doi:10.1021/ja993297d. 
  2. ^ Andrews, Ryan J.; Chitnis, Saurabh S.; Stephan, Douglas W. Carbonyl and olefin hydrosilylation mediated by an air-stable phosphorus(III) dication under mild conditions. Chemical Communications (Royal Society of Chemistry (RSC)). 2019, 55 (39): 5599–5602. ISSN 1359-7345. doi:10.1039/c9cc02460c. 

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