环臭氧

化合物

环臭氧是一种假设的同素异形体,其与臭氧分子一样有三颗氧原子,但并非角型而是成环状。

环臭氧
系统名
Trioxirane[1]
识别
CAS号 153851-84-4  checkY
PubChem 16206854
ChemSpider 13375217
SMILES
 
  • O1OO1
InChI
 
  • 1S/O3/c1-2-3-1
InChIKey XQOAKYYZMDCSIA-UHFFFAOYSA-N
性质
化学式 O3
摩尔质量 48 g·mol−1
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

简介

直到目前,不同的理论研究已确定环臭氧存在的可能。[2][3][4]另外也有实验指在1450℃以上在氧化镁表面重构中识别出微量环臭氧。[5]目前它并未能大量制造,而其中一个不成功的尝试是借助激光[6]另一个被提出的可能办法是在一个加以限制的空间内使其稳定,例如富勒烯[3]

科学家对其特性有一些预测,如其标准摩尔生成焓比臭氧高130 kJ mol−1,而它生成臭氧的活化能为95 kJ mol−1[7]另外又有建议指,若果环臭氧能大量制造,且它较为稳定,便可加入液态氧中以增加火箭燃料的比冲量[6]

参考

  1. ^ CID 16206854 - Compound Summary. PubChem Compound. USA: National Center for Biotechnology Information. Identification and Related Records. 11 July 2007 [21 October 2011]. (原始内容存档于2012-10-25). 
  2. ^ Xantheas, Sotiris; Atchity, Gregory; Elbert, Stephen; Ruedenberg, Klaus. Potential energy surfaces of ozone. I. J. Chem. Phys. 1991, 94 (12): 8054. Bibcode:1991JChPh..94.8054X. doi:10.1063/1.460140. 
  3. ^ 3.0 3.1 Sabirov, Denis; Igor, Shepelevich. Information entropy of oxygen allotropes. A still open discussion about the closed form of ozone. Computational and Theoretical Chemistry. 2015, 1073 (1): 61–66. doi:10.1016/j.comptc.2015.09.016. 
  4. ^ Lee, Timothy. On the energy separation between the open and cyclic forms of ozone. Chemical Physics Letters. 1990, 169 (6): 529–533. Bibcode:1990CPL...169..529L. doi:10.1016/0009-2614(90)85642-P. 
  5. ^ Plass, Richard; Kenneth Egan; Chris Collazo-Davila; Daniel Grozea; Eric Landree; Laurence D. Marks; Marija Gajdardziska-Josifovska. Cyclic Ozone Identified in Magnesium Oxide (111) Surface Reconstructions (PDF). Physical Review Letters. November 30, 1998, 81 (22): 4891–4894 [2010-06-05]. Bibcode:1998PhRvL..81.4891P. doi:10.1103/PhysRevLett.81.4891. (原始内容存档 (PDF)于2021-03-26). 
  6. ^ 6.0 6.1 Temple Researcher Attempting To Create Cyclic Ozone. Science Daily. February 8, 2005 [2010-06-05]. (原始内容存档于2016-11-29). 
  7. ^ Hoffmann, Roald. The story of O. The Ring. American Scientist. January–February 2004, 92 (1): 23–24. doi:10.1511/2004.1.23.