N-丙基二丁胺
N-丙基二丁胺是一种有机化合物,化学式为C11H25N。它可由二丁胺和丙醇在叔丁醇钾存在下、二氯化(4-甲基异丙苯)合钌二聚体催化下反应得到;[2]或和丙醛、三乙基硅烷在环辛二烯氯化铱二聚体催化下反应制得。[3]它可以和苦味酸成盐(mp. 115.8~116.2 °C)。[1]
N-丙基二丁胺 | |
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识别 | |
CAS号 | 36874-77-8 ![]() |
性质 | |
化学式 | C11H25N |
摩尔质量 | 171.32 g·mol−1 |
密度 | (d204)0.7622[1] |
沸点 | 193 °C(754 mmHg) 73~75 °C(8 mmHg)[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
参考文献
- ^ 1.0 1.1 1.2 Theodore Perrine. New Compounds. Di-n-butyl-n-propylamine. Journal of the American Chemical Society. 1944-02, 66 (2): 312–312 [2023-02-15]. ISSN 0002-7863. doi:10.1021/ja01230a600 (英语).
- ^ Arrey B. Enyong, Bahram Moasser. Ruthenium-Catalyzed N -Alkylation of Amines with Alcohols under Mild Conditions Using the Borrowing Hydrogen Methodology. The Journal of Organic Chemistry. 2014-08-15, 79 (16): 7553–7563 [2023-02-15]. ISSN 0022-3263. doi:10.1021/jo501273t (英语).
- ^ Tomoya Mizuta, Satoshi Sakaguchi, Yasutaka Ishii. Catalytic Reductive Alkylation of Secondary Amine with Aldehyde and Silane by an Iridium Compound. The Journal of Organic Chemistry. 2005-03-01, 70 (6): 2195–2199 [2023-02-15]. ISSN 0022-3263. doi:10.1021/jo0481708 (英语).