9-溴蒽
化合物
9-溴蒽是一种有机化合物,化学式为C14H9Br,它在标准状况下是固体。它可由蒽和溴化试剂(如四正丁基三溴化铵[4]或N,N,N',N'-四溴代-1,3-苯二磺酰胺[5])在一定条件下反应得到。
9-溴蒽 | |
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英文名 | 9-bromoanthracene |
识别 | |
CAS号 | 1564-64-3 ![]() |
性质 | |
化学式 | C14H9Br |
摩尔质量 | 257.13 g·mol⁻¹ |
外观 | 晶体 |
密度 | 1.479 g·cm−3 |
熔点 | 99—101 °C(372—374 K)[1] |
沸点 | 110 °C(383 K)(升华,0.05 Torr)[2] 212—215 °C(485—488 K)(4 Torr)[3] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
参考文献
- ^ Salellas, Juan F.; Orazi, Orfeo O. Nuclear halogenation with 1,3-dibromo-5,5-dimethylhydantoin. III. Polycyclic aromatic hydrocarbons. Anales de la Asociacion Quimica Argentina (1921-2001), 1951. 39: 175-183. ISSN: 0365-0375
- ^ Hans Dieter Becker, Lars Hansen, Kjell Andersson. Synthesis and photochemical isomerization of 1,2-di-9-anthrylethanol and 1,2-di-9-anthrylethanone. The Journal of Organic Chemistry. 1986-07, 51 (15): 2956–2961 [2019-06-14]. ISSN 0022-3263. doi:10.1021/jo00365a019. (原始内容存档于2019-09-18) (英语).
- ^ Messmer, A.; Varady, J.; Pinter, I. Halogenation and cyclizing dehydrogenation with tribromophenol-bromine. Acta Chimica Academiae Scientiarum Hungaricae, 1958. 15: 183-189. ISSN: 0001-5407
- ^ B. Alimenla, A. Kumar, L. Jamir, D. Sinha, U. B. Sinha. Microwave-induced reactions: an alternative route for chemical synthesis. Radiation Effects and Defects in Solids. 2006-12, 161 (12): 687–693 [2019-06-14]. ISSN 1042-0150. doi:10.1080/10420150600907657. (原始内容存档于2019-09-18) (英语).
- ^ Ramin Ghorbani-Vaghei, Hamid Jalili. Mild and Regioselective Bromination of Aromatic Compounds with N , N , N ′, N ′-Tetrabromobenzene-1,3-disulfonylamide and Poly( N -bromobenzene-1,3-disulfonylamide). Synthesis. 2005, (7): 1099–1102 [2019-06-14]. ISSN 0039-7881. doi:10.1055/s-2005-861851. (原始内容存档于2018-06-05) (英语).