2-甲基十二烷

化合物

2-甲基十二烷是一种有机化合物,化学式为C13H28,它是十三烷的同分异构体之一。它可由1-溴癸烷二异丙基锌的反应[3]、癸基溴化镁和2-溴丙烷的反应[4]1-十二烯三甲基铝的反应[5]制备。

2-甲基十二烷
识别
CAS号 1560-97-0  checkY
PubChem 15270
SMILES
 
  • CC(C)CCCCCCCCCC
性质
化学式 C13H28
摩尔质量 184.36 g·mol−1
密度 0.754 g·cm−3(20 °C)[1]
沸点 103—104 °C(376—377 K)(10.5 Torr)[1]
227.7±3.0 °C(760 Torr)[2]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ 1.0 1.1 Bashkirov, A. N.; Shaikhutdinov, E. M.; Gilyarovskaya, L. A. Oxidation of monomethyl-substituted paraffin hydrocarbons in the liquid phase in the presence of boric acid. Doklady Akademii Nauk SSSR, 1963. 148. 1309-1311. ISSN: 0002-3264.
  2. ^ Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (© 1994-2020 ACD/Labs). Retrieved from SciFinder. [2020-06-11].
  3. ^ Jun Terao, Hirohisa Todo, Hideyuki Watanabe, Aki Ikumi, Nobuaki Kambe. Nickel-Catalyzed Cross-Coupling Reaction of Alkyl Halides with Organozinc and Grignard Reagents with 1,3,8,10-Tetraenes as Additives. Angewandte Chemie International Edition. 2004-11-19, 43 (45): 6180–6182 [2020-06-19]. ISSN 1433-7851. doi:10.1002/anie.200460246 (英语). 
  4. ^ Gérard Cahiez, Christophe Chaboche, Christophe Duplais, Arianna Giulliani, Alban Moyeux. Cobalt‐Catalyzed Cross‐Coupling Reaction between Functionalized Primary and Secondary Alkyl Halides and Aliphatic Grignard Reagents. Advanced Synthesis & Catalysis. 2008-07-07, 350 (10): 1484–1488 [2020-06-19]. doi:10.1002/adsc.200800166 (英语). 
  5. ^ Stefan Mark, Nikola Gaidzik, Sven Doye, Markus Enders. Organochromium complexes as catalysts for the carboalumination of unactivated terminal olefins. Dalton Transactions. 2009, (25): 4875 [2020-06-19]. ISSN 1477-9226. doi:10.1039/b902609f (英语).