2-溴苯胺
化合物
2-溴苯胺是一种有机化合物，化学式为BrC6H4NH2。它可由2-硝基溴苯经水合肼[4]或氢气[5]还原制得。它和N-溴代丁二酰亚胺反应，得到2,4-二溴苯胺。[6]它和乙酸酐反应，得到2-乙酰氨基溴苯。[7]
| 2-溴苯胺 | |
|---|---|
| |
| 识别 | |
| CAS号 | 615-36-1 
|
| 性质 | |
| 化学式 | C6H6BrN |
| 摩尔质量 | 172.02 g·mol−1 |
| 密度 | 1.52 g·cm−3[1] |
| 熔点 | 31—32 °C（304—305 K）[2] |
| 沸点 | 126 °C（399 K）（29 torr）[3] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
- ^ Manuel A. V. Ribeiro da Silva, Ana I. M. C. L. Ferreira, José R. B. Gomes. Experimental and Computational Study on the Thermochemistry of Bromoanilines. Bulletin of the Chemical Society of Japan. 2006-12, 79 (12): 1852–1859 [2021-06-26]. ISSN 0009-2673. doi:10.1246/bcsj.79.1852. （原始内容存档于2019-08-21） （英语）.
- ^ Raymond G. Wallace, John M. Barker, Michael L. Wood. Migration to Electron-Deficient Nitrogen. A One Pot Synthesis of Aromatic and Heteroaromatic Amines from Carboxylic Acids. Synthesis. 1990, 1990 (12): 1143–1144 [2021-06-26]. ISSN 0039-7881. doi:10.1055/s-1990-27117. （原始内容存档于2018-06-02） （英语）.
- ^ Wataru Ando, Hidetoshi Tsumaki. Synthetic Application of Aminosilanes: Selective Bromination of Anilines via Reaction of Anilinosilanes with N -Bromosuccinimide. Synthesis. 1982, 1982 (04): 263–264 [2021-06-26]. ISSN 0039-7881. doi:10.1055/s-1982-29770. （原始内容存档于2018-06-03） （英语）.
- ^ Jing Lv, Zhengtang Liu, Zhengping Dong. Iron oxide modified N-doped porous carbon derived from porous organic polymers as a highly-efficient catalyst for reduction of nitroarenes. Molecular Catalysis. 2020-12, 498: 111249 [2021-06-26]. doi:10.1016/j.mcat.2020.111249 （英语）.
- ^ Dong-Fang Hou, Zhi-Feng Jiao, Zai-Peng Liang, Yun-Wei Wang, Xiao-Ning Guo, Xiang-Yun Guo. Selectivity control of Pt/SiC catalysts for photothermocatalytic hydrogenation of 3-nitrostyrene. Applied Surface Science. 2020-10, 526: 146616 [2021-06-26]. doi:10.1016/j.apsusc.2020.146616 （英语）.
- ^ Rama Moorthy Appa, Bandameeda Ramesh Naidu, Jangam Lakshmidevi, Jyothi Vantikommu, Katta Venkateswarlu. Added catalyst-free, versatile and environment beneficial bromination of (hetero)aromatics using NBS in WEPA. SN Applied Sciences. 2019-10, 1 (10) [2021-06-26]. ISSN 2523-3963. doi:10.1007/s42452-019-1274-x （英语）.
- ^ Jaeyoung Ban, Minkyung Lim, Saira Shabbir, Junghyun Baek, Hakjune Rhee. Site-Specific Synthesis of Carbazole Derivatives through Aryl Homocoupling and Amination. Synthesis. 2020-03, 52 (06): 917–927 [2021-06-26]. ISSN 0039-7881. doi:10.1055/s-0039-1690759 （英语）.