1,4-苯二硼酸

化合物

1,4-苯二硼酸是一种有机化合物,化学式为C6H8B2O4。它可以1,4-二溴苯硼酸三甲酯为原料反应制得。[1]也有文献报道了通过1,4-二(三甲基锡基)苯和BH3-THF的反应来制备1,4-苯二硼酸。[2]它和溴苯在Pd(II)催化及碳酸钾存在下反应,可以得到1,1':4',1''-三联苯[3]它可以被氢化铝锂还原为Li2[H3BC6H4BH3]。[4]

1,4-苯二硼酸
别名 对苯二硼酸
识别
CAS号 4612-26-4  checkY
性质
化学式 C6H8B2O4
摩尔质量 165.75 g·mol−1
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ Kensuke Nakashima, Takeshi Shimizu, Yoshinobu Kamakura, Akira Hinokimoto, Yasutaka Kitagawa, Hirofumi Yoshikawa, Daisuke Tanaka. A new design strategy for redox-active molecular assemblies with crystalline porous structures for lithium-ion batteries. Chemical Science. 2020, 11 (1): 37–43 [2022-06-20]. ISSN 2041-6520. PMC 7067258 . PMID 32190257. doi:10.1039/C9SC04175C (英语). 
  2. ^ Sandra D. Mandolesi, Santiago E. Vaillard, Julio C. Podestá, Roberto A. Rossi. Synthesis of Benzene- and Pyridinediboronic Acids via Organotin Compounds. Organometallics. 2002-10-01, 21 (22): 4886–4888 [2022-06-20]. ISSN 0276-7333. doi:10.1021/om020163r. (原始内容存档于2022-01-31) (英语). 
  3. ^ Yu-Xin Ye, Wan-Long Liu, Bao-Hui Ye. A highly efficient and recyclable Pd(II) metallogel catalyst: A new scaffold for Suzuki-Miyaura coupling. Catalysis Communications. 2017-01, 89: 100–105 [2022-06-20]. doi:10.1016/j.catcom.2016.10.017. (原始内容存档于2018-06-29) (英语). 
  4. ^ Audrey Ledoux, Paolo Larini, Christophe Boisson, Vincent Monteil, Jean Raynaud, Emmanuel Lacôte. Polyboramines for Hydrogen Release: Polymers Containing Lewis Pairs in their Backbone. Angewandte Chemie International Edition. 2015-12-21, 54 (52): 15744–15749 [2022-06-20]. ISSN 1433-7851. doi:10.1002/anie.201508395. (原始内容存档于2022-06-20) (英语).