1,2-二苯基乙酮

化合物

1,2-二苯基乙酮是一种有机化合物,化学式为C14H12O。它可由安息香[1]二苯基乙二酮[2]脱氧得到。它和1,2-二溴苯碳酸铯三苯基膦乙酸钯存在下反应,可以得到2,3-二苯基苯并呋喃維基數據所列Q82029595[3]

1,2-二苯基乙酮
别名 脱氧安息香
二苯乙酮
识别
CAS号 451-40-1  checkY
SMILES
 
  • O=C(C=1C=CC=CC1)CC=2C=CC=CC2
性质
化学式 C14H12O
摩尔质量 196.24 g·mol−1
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ Uranga, Jorge G.; Chiosso, Antonella F.; Santiago, Ana N. One-step selective deoxygenation of alcohols from acyloins. RSC Advances, 2013. doi:10.1039/c3ra40343b.
  2. ^ Lin, Wei; Hu, Ming-Hua; Feng, Xian; Fu, Lei; Cao, Cheng-Pao; Huang, Zhi-Bin; Shi, Da-Qing. Selective reduction of carbonyl groups in the presence of low-valent titanium reagents. Tetrahedron Letters, 2014. doi:10.1016/j.tetlet.2014.02.072.
  3. ^ Terao, Yoshito; Satoh, Tetsuya; Miura, Masahiro; Nomura, Masakatsu. Palladium-Catalyzed Cross-Coupling of Benzyl Ketones and α,β-Unsaturated Carbonyl and Phenolic Compounds with o-Dibromobenzenes to Produce Cyclic Products. Bulletin of the Chemical Society of Japan, 1999. doi:10.1246/bcsj.72.2345.