高氯酸钆
化合物
高氯酸钆是一种无机化合物,化学式为Gd(ClO4)3。它可由氧化钆和高氯酸(70~72%)在80 °C反应得到。[1]它可以和二噁烷形成无色的Gd(ClO4)3·9H2O·4C4H8O2配合物晶体。[2]它和myo-肌醇、乙酸钠、氢氧化钠反应,可以得到含巨型分子簇{Gd140}的配合物。[1]它和氯化铬、2,2'-联吡啶在pH=5.1下反应,可以得到[GdCr(bipy)2(OH)2(H2O)6](ClO4)4·2H2O。[3]
高氯酸钆 | ||
---|---|---|
| ||
识别 | ||
CAS号 | 14017-52-8(无水) ![]() 15201-56-6(八水) ![]() | |
性质 | ||
化学式 | Cl3GdO12 | |
摩尔质量 | 455.6 g·mol−1 | |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
参考文献
- ^ 1.0 1.1 Xiu-Ying Zheng, You-Hong Jiang, Gui-Lin Zhuang, Da-Peng Liu, Hong-Gang Liao, Xiang-Jian Kong, La-Sheng Long, Lan-Sun Zheng. A Gigantic Molecular Wheel of {Gd 140 }: A New Member of the Molecular Wheel Family. Journal of the American Chemical Society. 2017-12-20, 139 (50): 18178–18181 [2023-03-15]. ISSN 0002-7863. doi:10.1021/jacs.7b11112. (原始内容存档于2023-03-15) (英语).
- ^ Vicentini, Geraldo; Perrier, Madeleine; Giesbrecht, Ernesto. The reaction of dioxane with the perchlorate hydrates of a few transition metals. Chemische Berichte, 1961. 94: 1153-1155.
- ^ Zhong‐Yi Li, Xiao‐Qun Wang, Jian‐Jun Zhang, Shu‐Qin Liu, Jun Ni, Ying‐Ji Sun. Synthesis, Structures, and Magnetic Properties of Binuclear [CrLn] (Ln = Gd or Dy) and Trinuclear [Cr 2 Ln] (Ln = Gd, Dy, or Tb) Heterometallic Clusters with 2,2′‐Bipyridine as Ligand. European Journal of Inorganic Chemistry. 2015-12, 2015 (34): 5702–5707 [2023-03-15]. ISSN 1434-1948. doi:10.1002/ejic.201500786 (英语).