间三联苯
间三联苯是一种有机化合物,化学式为C18H14,是三联苯的同分异构体之一。它可由1,3-二溴苯和苯硼酸的铃木偶联反应制得。[2]它和氨基锂在液氨中发生Birch还原反应,可以得到1,3-二苯基-1,4-环己二烯。[3]
间三联苯 | |
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识别 | |
CAS号 | 92-06-8 ![]() |
性质 | |
化学式 | C18H14 |
摩尔质量 | 230.3 g·mol−1 |
熔点 | 86.7 °C(359.8 K)[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
参考文献
- ^ Shigeru Ozasa, Yasuhiro Fujioka, Hiromi Hashino, Naoko Kimura, Eiichi Ibuki. Syntheses and spectral properties of several branched-chain polyphenyls containing 1,3,5-trisubstituted ring(s).. Chemical and Pharmaceutical Bulletin. 1983, 31 (7): 2313–2320 [2021-06-24]. ISSN 0009-2363. doi:10.1248/cpb.31.2313. (原始内容存档于2018-06-13) (英语).
- ^ Sandeep Kumar Dey, Dennis Dietrich, Susann Wegner, Beatriz Gil-Hernández, Sarvesh Shyam Harmalkar, Nader de Sousa Amadeu, Christoph Janiak. Palladium Nanoparticle-Immobilized Porous Polyurethane Material for Quick and Efficient Heterogeneous Catalysis of Suzuki-Miyaura Cross-Coupling Reaction at Room Temperature. ChemistrySelect. 2018-02-07, 3 (5): 1365–1370 [2021-06-24]. doi:10.1002/slct.201702083 (英语).
- ^ Peter W. Rabideau, Zbigniew Marcinow. John Wiley & Sons, Inc. , 编. The Birch Reduction of Aromatic Compounds. Hoboken, NJ, USA: John Wiley & Sons, Inc. 1992-06-12: 1–334 [2021-06-24]. ISBN 9780471264187. doi:10.1002/0471264180.or042.01 (英语).