羊茅麦角碱
化合物
羊茅麦角碱((8β,10β)-6,8-二甲基麦角灵)是一种有机化合物,化学式为C16H20N2,它是一种麥角靈真菌分离物。[2]它可以2-溴-3-硝基苄溴为原料经多步反应、柱分离制得。[1]
羊茅麦角碱 | |
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IUPAC名 6,8β-Dimethylergoline | |
系统名 (6aR,9R,10aR)-7,9-Dimethyl-4,6,6a,7,8,9,10,10a-octahydroindolo[4,3-fg]quinoline | |
别名 | 狐茅麦角碱 |
识别 | |
CAS号 | 569-26-6 ![]() |
PubChem | 332915 |
ChemSpider | 294963 |
SMILES |
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性质 | |
化学式 | C16H20N2 |
摩尔质量 | 240.34 g·mol−1 |
外观 | 白色固体[1] |
熔点 | 236—240 °C(509—513 K)[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
参考文献
- ^ 1.0 1.1 1.2 Liu, Haichao; Zhang, Xiwu; Shan, Dong; Pitchakuntla, Mallesham; Ma, Yongfan; Jia, Yanxing. Total Syntheses of Festuclavine, Pyroclavine, Costaclavine, epi-Costaclavine, Pibocin A, 9-Deacetoxyfumigaclavine C, Fumigaclavine G, and Dihydrosetoclavine. Organic Letters (American Chemical Society (ACS)). 2017-06-08, 19 (12): 3323–3326. ISSN 1523-7060. doi:10.1021/acs.orglett.7b01504.
- ^ Wallwey, C; Matuschek, M; Xie, XL; Li, SM. Ergot alkaloid biosynthesis in Aspergillus fumigatus: Conversion of chanoclavine-I aldehyde to festuclavine by the festuclavine synthase FgaFS in the presence of the old yellow enzyme FgaOx3. Organic & Biomolecular Chemistry. 2010, 8 (15): 3500–8. PMID 20526482. doi:10.1039/c003823g.