禾本甾醇

禾本甾醇(英語:Gramisterol,或称作24-亚甲基冠影掌烯醇,24-Methylenelophenol,化学名4α-甲基-5α-麦角甾-7,24(28)-二烯-3β-醇,4α-Methyl-5α-ergosta-7,24(28)-dien-3β-ol)是植物真菌甾醇代谢中间产物[1],分子式C29H48O,可由酶HYD1催化4α-甲基粪生甾醇而来[2]

禾本甾醇
识别
CAS号 1176-52-9
PubChem 5283640
ChemSpider 4446733
SMILES
 
  • C[C@@H]1[C@H](CC[C@]2([C@H]1CC=C3[C@@H]2CC[C@]4([C@H]3CC[C@@H]4[C@H](C)CCC(=C)C(C)C)C)C)O
Beilstein 3655840
ChEBI 29107
KEGG C11522
性质
化学式 C29H48O
摩尔质量 412.69 g·mol−1
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ Ullah, H; Khan, A; Rehman, NU; Halim, SA; Khan, H; Khan, I; Csuk, R; Al-Rawahi, A; Al-Hatmi, S; Al-Harrasi, A. Lophenol and lathosterol from resin of Commiphora kua possess hepatoprotective effects in vivo.. Journal of Ethnopharmacology. 24 April 2020, 252: 112558. PMID 31926985. S2CID 210166705. doi:10.1016/j.jep.2020.112558. 
  2. ^ Kuchta, T; Bartková, K; Kubinec, R. Ergosterol depletion and 4-methyl sterols accumulation in the yeast Saccharomyces cerevisiae treated with an antifungal, 6-amino-2-n-pentylthiobenzothiazole.. Biochemical and Biophysical Research Communications. 30 November 1992, 189 (1): 85–91. PMID 1449509. doi:10.1016/0006-291x(92)91529-y.