砷化铋
砷化铋是一种无机化合物，化学式为BiAs。它的α型[1]和β型[2]结构均有理论计算的报道。
| 砷化铋 | |
|---|---|
| 英文名 | bismuth arsenide |
| 识别 | |
| CAS号 | 12322-23-5 
|
| 性质 | |
| 化学式 | BiAs |
| 摩尔质量 | 283.9 g·mol⁻¹ |
| 外观 | 固体 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
制备
砷化铋可由三氯化铋的甲苯溶液和三(三甲基硅基)砷在室温反应得到：[3]
- BiCl3 + As[Si(CH3)3]3 → BiAs + 3(CH3)3SiCl
参考文献
- ^ Wen-Zhi Xiao, Gang Xiao, Qing-Yan Rong, Ling-Ling Wang. New two-dimensional V-V binary compounds with a honeycomb-like structure: a first-principles study. Materials Research Express. 2018-03-07, 5 (3): 035903 [2020-04-25]. ISSN 2053-1591. doi:10.1088/2053-1591/aab06c.
- ^ C. Y. Wu, L. Sun, J. C. Han, H. R. Gong. Band structure, phonon spectrum, and thermoelectric properties of β-BiAs and β-BiSb monolayers. Journal of Materials Chemistry C. 2020, 8 (2): 581–590 [2020-04-25]. ISSN 2050-7526. doi:10.1039/C9TC04842A （英语）.
- ^ Geoff C. Allen, Claire J. Carmalt, Alan H. Cowley, Andrew L. Hector, Smuruthi Kamepalli, Yvonne G. Lawson, Nicholas C. Norman, Ivan P. Parkin, Laura K. Pickard. Preparation and Characterization of a Material of Composition BiP (Bismuth Phosphide) and Other Intergroup 15 Element Phases. Chemistry of Materials. 1997-06, 9 (6): 1385–1392 [2020-04-25]. ISSN 0897-4756. doi:10.1021/cm960606f. （原始内容存档于2022-01-17） （英语）.