氟氯二溴甲烷

化合物

氟氯二溴甲烷是一种有机化合物,化学式为CBr2ClF。它可由氟氯溴乙酸银和在180~260 °C反应,或由氟二氯甲烷在650 °C溴化制得。[2]它可用于在有机物中引入氟氯溴甲基。[3][4]

氟氯二溴甲烷
英文名 dibromochlorofluoromethane
别名 FC 11B2
识别
CAS号 353-55-9  checkY
性质
化学式 CBr2ClF
摩尔质量 226.27 g·mol−1
沸点 80.3 °C[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ Reid, Robert J.; Hanson, Edward S.; Pikna, Raymond J. Dibromochlorofluoromethane from dichlorofluoromethane. 1956 US 2755314.
  2. ^ Katritzky, A.R.; Gilchrist, T.L.; Meth-Cohn, O.; Rees, C.W. Comprehensive Organic Functional Group Transformations. Comprehensive Organic Functional Group Transformations. Elsevier Science. 1995: 227 [2021-10-27]. ISBN 978-0-08-042704-1. (原始内容存档于2021-10-27).  |issue=被忽略 (帮助)
  3. ^ Clavel, Jean Louis; Langlois, Bernard; Nantermet, Roland; Tordeux, Marc; Wakselman, Claude. Reactions of bromotrifluoromethane and related halides. Part 12. Transformation of disulfides into perfluoroalkyl sulfides in the presence of sulfoxylate anion radical precursors. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1992. 24: 3371-3375.
  4. ^ Jaroslav Kvíčala, Jan Štambaský, Martin Skalický, Oldřich Paleta. Preparation of fluorohalomethylmagnesium halides using highly active magnesium metal and their reactions. Journal of Fluorine Chemistry. 2005-10, 126 (9-10): 1390–1395 [2021-10-27]. doi:10.1016/j.jfluchem.2005.07.016. (原始内容存档于2018-06-13) (英语).