乙酰丙酮钕

乙酰丙酮钕
英文名	Neodymium acetylacetonate
识别
CAS号	14589-38-9
性质
化学式	C15H21NdO6
摩尔质量	441.57 g·mol−1
外观	粉色粉末
熔点	150 °C（423 K）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

乙酰丙酮钕是一种配位化合物，化学式为Nd(C₅H₇O₂)₃，或简写为Nd(acac)₃，它的不稳定常数（logY_n）分别为2.89、4.15和5.26（对应n=1, 2, 3）。^[2]它可由三烷氧基钕和乙酰丙酮反应制得，^[3]或通过金属钕在乙酰丙酮中电解得到。^[4]它的二水合物和羰基铼配合物Re(CO)₃X(4,4'-bipy)（X=Cl, Br）反应，可以得到Re(CO)₃X(4,4'-bipy)Nd(acac)₃。^[5]

参考文献

^ ^1.0 ^1.1 Pierson, H.O. Handbook of Chemical Vapor Deposition: Principles, Technology and Applications. Materials Science and Process Technology. Elsevier Science. 1999: 92 [2021-09-16]. ISBN 978-0-8155-1743-6. （原始内容存档于2021-10-17）.
^ N.K. Dutt, P. Banyopadhyay. Chemistry of the lanthanons—XIII. Journal of Inorganic and Nuclear Chemistry. 1964-05, 26 (5): 729–736 [2021-09-20]. doi:10.1016/0022-1902(64)80316-X. （原始内容存档于2018-06-24）（英语）.
^ Gavrilenko, V. V.; Chekulaeva, L. A.; Savitskaya, I. A.; Garbuzova, I. A. Synthesis of yttrium, lanthanum, neodymium, praseodymium and lutetium alkoxides and acetylacetonates（俄文）. Izvestiya Akademi Nauk, Seriya Khimicheskaya, 1992. 11: 2490-2493. ISSN 1026-3500.
^ Panyushkin, V. T.; Frolov, V. Yu.; Zelenov, V. I. Electrochemical synthesis of rare-earth metal acetylacetonates. Russian Journal of General Chemistry (Translation of Zhurnal Obshchei Khimii), 2001. 71 (8): 1318.
^ Shapoval, A. N.; Bobukhov, D. V.; Rusakova, N. V.; Shtemenko, A. V.; Snurnikova, O. V.; Korovin, Yu. V. Synthesis and spectral-luminescent properties of mono- (Re⁺) and heteronuclear (Re⁺-Ln³⁺) tricarbonyl-halo complexes（俄文）. Ukrainskii Khimicheskii Zhurnal (Russian Edition), 2007. 73 (9-10): 34-36. ISSN 0041-6045.

[Pierson-1] 1.0 ^1.1 Pierson, H.O. Handbook of Chemical Vapor Deposition: Principles, Technology and Applications. Materials Science and Process Technology. Elsevier Science. 1999: 92 [2021-09-16]. ISBN 978-0-8155-1743-6. （原始内容存档于2021-10-17）.

[2] N.K. Dutt, P. Banyopadhyay. Chemistry of the lanthanons—XIII. Journal of Inorganic and Nuclear Chemistry. 1964-05, 26 (5): 729–736 [2021-09-20]. doi:10.1016/0022-1902(64)80316-X. （原始内容存档于2018-06-24）（英语）.

[3] Gavrilenko, V. V.; Chekulaeva, L. A.; Savitskaya, I. A.; Garbuzova, I. A. Synthesis of yttrium, lanthanum, neodymium, praseodymium and lutetium alkoxides and acetylacetonates（俄文）. Izvestiya Akademi Nauk, Seriya Khimicheskaya, 1992. 11: 2490-2493. ISSN 1026-3500.

[4] Panyushkin, V. T.; Frolov, V. Yu.; Zelenov, V. I. Electrochemical synthesis of rare-earth metal acetylacetonates. Russian Journal of General Chemistry (Translation of Zhurnal Obshchei Khimii), 2001. 71 (8): 1318.

[5] Shapoval, A. N.; Bobukhov, D. V.; Rusakova, N. V.; Shtemenko, A. V.; Snurnikova, O. V.; Korovin, Yu. V. Synthesis and spectral-luminescent properties of mono- (Re⁺) and heteronuclear (Re⁺-Ln³⁺) tricarbonyl-halo complexes（俄文）. Ukrainskii Khimicheskii Zhurnal (Russian Edition), 2007. 73 (9-10): 34-36. ISSN 0041-6045.

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