三溴碘甲烷
三溴碘甲烷是一种有机化合物,化学式为CBr3I,它可由四溴化碳和碘化钠在丙酮中反应得到,产率30%,反应的其余产物为溴代的丙酮以及痕量的溴三碘甲烷。[2]硝基三溴甲烷和少量碘化钾的反应也会生成三溴碘甲烷。[3]它可用于在有机物中引入三溴甲基。[4]
三溴碘甲烷 | |
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识别 | |
CAS号 | 14349-80-5 ![]() |
性质 | |
化学式 | CBr3I |
摩尔质量 | 378.63 g·mol−1 |
密度 | 3.659±0.06 g·cm−3(20 °C)[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
参考文献
- ^ Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (© 1994-2021 ACD/Labs). Retrieved from SciFinder. [2021-10-26].
- ^ Kennedy, John Rider; Vickrey, Thomas M.; Somayajulu, G. R.; Zwolinski, Bruno J. Synthesis of dichloroiodomethane, trichloroiodomethane, dibromoiodomethane, and tribromoiodomethane. Journal of Chemical & Engineering Data (American Chemical Society (ACS)). 1979, 24 (3): 251–252. ISSN 0021-9568. doi:10.1021/je60082a003.
- ^ Jacobson, C.A.; Hampel, C.A.; Weaver, E.C. Encyclopedia of Chemical Reactions. Encyclopedia of Chemical Reactions. Reinhold Publishing Corporation. 1959 [2021-10-26]. (原始内容存档于2021-10-27).
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被忽略 (帮助) - ^ Siddiqi, Suhaib M.; Glover, William Roy; Scipioni, Lawrence; Murtagh, Katelyn Marie; Putta, Mallikarjuna Reddy. Heavy atom labeled nucleosides, nucleotides, and nucleic acid polymers, and uses thereof. 2014. WO 2014078652 A1.