顺丁烯二腈二硫醇镍四乙基铵
顺丁烯二腈二硫醇镍四乙基铵是一种配位化合物,化学式为[N(C2H5)4]2[Ni(C4N2S2)2]。它是三斜晶系晶体,空间群P1,晶胞参数a=7.5608,b=8.7017,c=12.626 Å,α=93.73,β=104.27,γ=75.257°,Z=1。[1]它和硫酸银在膦配体的存在下反应,可以得到[Ag(PR3)2]2[Ni(C4N2S2)2]。[2]
顺丁烯二腈二硫醇镍四乙基铵 | |
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别名 | 顺丁烯二腈二硫醇镍(II)二(四乙基铵) 四乙基马来腈二硫醇镍铵 |
识别 | |
CAS号 | 15665-90-4 ![]() |
性质 | |
密度 | 1.286 g·cm−3 |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
三价镍化合物[N(C2H5)4][Ni(C4N2S2)2]是已知的。[3]
参考文献
- ^ C. Mahadevan, M. Seshasayee, A. Radha, P. T. Manoharan. Structure of bis(tetraethylammonium) bis[dimercaptomaleodinitrilato(2–)-S,S']nickelate(II), [N(C2H5)4]2[Ni(C4N2S2)2]. Acta Crystallographica Section C Crystal Structure Communications. 1984-12-15, 40 (12): 2032–2034 [2021-08-24]. doi:10.1107/S0108270184010519. (原始内容存档于2021-08-24).
- ^ Kyoung-Tae Youm, Youngmee Kim, Youngkyu Do, Moo-Jin Jun. Design and properties of mixed metal multinuclear molecules. Inorganica Chimica Acta. 2000-12, 310 (2): 203–209 [2021-08-24]. doi:10.1016/S0020-1693(00)00284-X. (原始内容存档于2020-02-09) (英语).
- ^ P. Kuppusamy, P. T. Manoharan, C. Mahadevan, M. Seshasayee. Crystal and molecular structure ofN-methylphenazinium bis(maleodinitriledithiolato)nickelate(III), [NMP]+ [Ni(mnt)2]?. Journal of Crystallographic and Spectroscopic Research. 1985-08, 15 (4): 359–376 [2021-08-24]. ISSN 0277-8068. doi:10.1007/BF01160728 (英语).