三氟甲磺酸锰

三氟甲磺酸锰是一种无机化合物,化学式为Mn(CF3SO3)2。它可由和无水三氟甲磺酸在氩气保护下于乙腈中反应制得,或通过碳酸锰三氟甲磺酸在水中反应得到。[1]它的乙醇溶液与1,4-二(1-咪唑基)苯(bib)的二氯甲烷溶液扩散结晶,可以得到{[Mn(bib)2(CF3SO3)2](CH2Cl2)4}n[3]

三氟甲磺酸锰

识别
CAS号 55120-76-8(无水)  checkY
1301749-91-6(六水)  checkY
性质
化学式 C2F6MnO6S2
摩尔质量 353.08 g·mol−1
外观 白色吸湿性粉末(无水)[1]
白色粉末(六水)[2]
熔点 > 400 °C(无水)[1]
86 °C(六水)[2]
溶解性 可溶于乙腈,微溶于乙醇,难溶于丙酮和乙醚[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ 1.0 1.1 1.2 1.3 Miao, Cheng-Xia; Sun, Wei, Manganese Bis(trifluoromethanesulfonate), Chichester, UK: John Wiley & Sons, Ltd, 2012-03-15, doi:10.1002/047084289x.rn01455 
  2. ^ 2.0 2.1 Sniekers, Jeroen; Malaquias, João C.; Van Meervelt, Luc; Fransaer, Jan; Binnemans, Koen. Manganese-containing ionic liquids: synthesis, crystal structures and electrodeposition of manganese films and nanoparticles. Dalton Transactions (Royal Society of Chemistry (RSC)). 2017, 46 (8): 2497–2509. ISSN 1477-9226. doi:10.1039/c6dt04781e. 
  3. ^ Ye, Gan; Zou, Kang-Yu; Yang, Ying; Wang, Jun-Jie; Gou, Xiao-Feng; Li, Zuo-Xi. Anion effect on the topological frameworks of a series of manganese coordination polymers based on 1,4-bis(imidazol-1-yl)-benzene: Syntheses, crystal structures and magnetic properties. Journal of Solid State Chemistry (Elsevier BV). 2015, 225: 31–40. ISSN 0022-4596. doi:10.1016/j.jssc.2014.11.015. 

拓展阅读

  • Amelia M. Wheaton, Jill A. Chipman, Michael D. Roy, and John. F. Berry. Metal–Metal Bond Umpolung in Heterometallic Extended Metal Atom Chains. Inorg. Chem. 2022, 61, 38, 15058–15069. doi:10.1021/acs.inorgchem.2c02118.